- A(B), (C) only
- B(A), (B) only
- C(A), (B), (D) only
- D(C), (D) only
View written solutionFree
Correct answer: A
-
Check statement (A): Compare for Fe and Mn.
- For iron:
- For manganese:
Since the reduction potential for iron is not greater than manganese.
So, (A) is false.
-
Check statement (B): Higher oxidation states of first-row -block elements are stabilized by oxide ion.
This is a standard trend in transition-metal chemistry. Oxygen, being highly electronegative and small, stabilizes metals in high oxidation states through strong bonds.
Examples:
- with V in
- with Cr in
- with Mn in
Hence, (B) is true.
-
Check statement (C): Aqueous solution of can liberate hydrogen from dilute acid.
is a strong reducing agent.
Compare standard potentials:
Since oxidation of to is favorable, it can reduce to :
Therefore, (C) is true.
-
Check statement (D): Magnetic moment of is observed between BM.
Electronic configuration of V:
Number of unpaired electrons, .
Spin-only magnetic moment:
The observed value is around BM, not BM.
So, (D) is false.
-
Conclusion:
Correct statements are:
Hence the correct option is:
More from D and F Block Elements
- Given below are two statement: one is labelled as Assertion and the other is labelled as Reason Assertion A: electrons can participate in bonding to a far greater extent than …2023 · MCQ
- The pair of lanthanides in which both elements have high third - ionization energy is :2023 · MCQ
- In Chromyl chloride, the oxidation state of chromium is .2023 · Numerical
- The total change in the oxidation state of manganese involved in the reaction of and potassium iodide in the acidic medium is .2023 · Numerical
- An ammoniacal metal salt solution gives a brilliant red precipitate on addition of dimethylglyoxime. The metal ion is :2023 · MCQ
- Which one amongst the following are good oxidizing agents? A. Sm B. Ce C. Ce D. Tb Choose the most appropriate answer from the options given below :2023 · MCQ
- How many of the following metal ions have similar value of spin only magnetic moment in gaseous state? (Given : Atomic number V, 23; Cr, 24; Fe, 26; Ni, 28) V , Cr , Fe , Ni 2023 · Numerical
- A chloride salt solution acidified with dil.HNO gives a curdy white precipitate, [A], on addition of AgNO . [A] on treatment with NH OH gives a clear solution B. A and B are respectively :2023 · MCQ