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D and F Block Elements question

2023 · 10 Apr · Shift 1 · Q6
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D and F Block Elements question

2023 · 10 Apr · Shift 1 · Q6

JEE MainChemistryD and F Block ElementsMCQ+4 / −1
Which of the following statements are correct? (A) The M 3+^{3+}3+/M 2+^{2+}2+ reduction potential for iron is greater than manganese. (B) The higher oxidation states of first row d-block elements get stabilized by oxide ion. (C) Aqueous solution of Cr 2+^{2+}2+ can liberate hydrogen from dilute acid. (D) Magnetic moment of V 2+^{2+}2+ is observed between 4.4 - 5.2 BM. Choose the correct answer from the options given below :
  1. A
    (B), (C) only
  2. B
    (A), (B) only
  3. C
    (A), (B), (D) only
  4. D
    (C), (D) only
View written solutionFree

Correct answer: A

  1. Check statement (A): Compare E∘(M3+/M2+)E^\circ(\text{M}^{3+}/\text{M}^{2+})E∘(M3+/M2+) for Fe and Mn.

    • For iron: Fe3++e−→Fe2+,E∘=+0.77 V\text{Fe}^{3+} + e^- \rightarrow \text{Fe}^{2+}, \quad E^\circ = +0.77\,\text{V}Fe3++e−→Fe2+,E∘=+0.77V
    • For manganese: Mn3++e−→Mn2+,E∘≈+1.51 V\text{Mn}^{3+} + e^- \rightarrow \text{Mn}^{2+}, \quad E^\circ \approx +1.51\,\text{V}Mn3++e−→Mn2+,E∘≈+1.51V

    Since 1.51>0.771.51 > 0.771.51>0.77 the reduction potential for iron is not greater than manganese.

    So, (A) is false.

  2. Check statement (B): Higher oxidation states of first-row ddd-block elements are stabilized by oxide ion.

    This is a standard trend in transition-metal chemistry. Oxygen, being highly electronegative and small, stabilizes metals in high oxidation states through strong M−OM-OM−O bonds.

    Examples:

    • V2O5\text{V}_2\text{O}_5V2​O5​ with V in +5+5+5
    • CrO3\text{CrO}_3CrO3​ with Cr in +6+6+6
    • Mn2O7\text{Mn}_2\text{O}_7Mn2​O7​ with Mn in +7+7+7

    Hence, (B) is true.

  3. Check statement (C): Aqueous solution of Cr2+\text{Cr}^{2+}Cr2+ can liberate hydrogen from dilute acid.

    Cr2+\text{Cr}^{2+}Cr2+ is a strong reducing agent.

    Compare standard potentials: Cr3++e−→Cr2+,E∘=−0.41 V\text{Cr}^{3+} + e^- \rightarrow \text{Cr}^{2+}, \quad E^\circ = -0.41\,\text{V}Cr3++e−→Cr2+,E∘=−0.41V 2H++2e−→H2,E∘=0.00 V2\text{H}^+ + 2e^- \rightarrow \text{H}_2, \quad E^\circ = 0.00\,\text{V}2H++2e−→H2​,E∘=0.00V

    Since oxidation of Cr2+\text{Cr}^{2+}Cr2+ to Cr3+\text{Cr}^{3+}Cr3+ is favorable, it can reduce H+\text{H}^+H+ to H2\text{H}_2H2​: 2Cr2++2H+→2Cr3++H22\text{Cr}^{2+} + 2\text{H}^+ \rightarrow 2\text{Cr}^{3+} + \text{H}_22Cr2++2H+→2Cr3++H2​

    Therefore, (C) is true.

  4. Check statement (D): Magnetic moment of V2+\text{V}^{2+}V2+ is observed between 4.4−5.24.4 - 5.24.4−5.2 BM.

    Electronic configuration of V: V:[Ar]3d34s2\text{V}: [\text{Ar}]3d^34s^2V:[Ar]3d34s2 V2+:[Ar]3d3\text{V}^{2+}: [\text{Ar}]3d^3V2+:[Ar]3d3

    Number of unpaired electrons, n=3n = 3n=3.

    Spin-only magnetic moment: μ=n(n+2)=3(3+2)=15≈3.87 BM\mu = \sqrt{n(n+2)} = \sqrt{3(3+2)} = \sqrt{15} \approx 3.87\,\text{BM}μ=n(n+2)​=3(3+2)​=15​≈3.87BM

    The observed value is around 3.8−4.03.8 - 4.03.8−4.0 BM, not 4.4−5.24.4 - 5.24.4−5.2 BM.

    So, (D) is false.

  5. Conclusion:

    Correct statements are: (B),(C) only\boxed{(B), (C)\text{ only}}(B),(C) only​

    Hence the correct option is: A\boxed{\text{A}}A​

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