JEE MainChemistryD and F Block ElementsMCQ+4 / −1
During the reaction of permanganate with thiosulphate, the change in oxidation of manganese occurs by value of 3. Identify which of the below medium will favour the reaction.
- Aaqueous neutral
- Bboth aqueous acidic and faintly alkaline
- Cboth aqueous acidic and neutral
- Daqueous acidic
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Correct answer: A
- Find the oxidation state change required for manganese
In permanganate, manganese is in the oxidation state:
The question says the change in oxidation state of manganese occurs by 3. So manganese must go from:
This corresponds to formation of manganese dioxide:
- Recall reduction products of permanganate in different media
Permanganate gives different products depending on the medium:
-
Acidic medium: Change in oxidation state:
-
Neutral or faintly alkaline medium: Change in oxidation state:
-
Strongly alkaline medium: Change in oxidation state:
- Match with the condition in the question
Since the oxidation state change is 3, the reaction must occur in the medium where permanganate is reduced to .
That happens in:
- Check the options
- A: aqueous neutral — correct, since neutral medium gives .
- B: both aqueous acidic and faintly alkaline — incorrect, acidic gives change of 5.
- C: both aqueous acidic and neutral — incorrect, acidic again gives change of 5.
- D: aqueous acidic — incorrect.
- Final answer
The medium that favours oxidation-state change of manganese by 3 is aqueous neutral.
So the correct option is:
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