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D and F Block Elements question

2023 · 6 Apr · Shift 2 · Q9
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D and F Block Elements question

2023 · 6 Apr · Shift 2 · Q9

JEE MainChemistryD and F Block ElementsMCQ+4 / −1
During the reaction of permanganate with thiosulphate, the change in oxidation of manganese occurs by value of 3. Identify which of the below medium will favour the reaction.
  1. A
    aqueous neutral
  2. B
    both aqueous acidic and faintly alkaline
  3. C
    both aqueous acidic and neutral
  4. D
    aqueous acidic
View written solutionFree

Correct answer: A

  1. Find the oxidation state change required for manganese

In permanganate, manganese is in the oxidation state: Mn in MnO4−=+7\text{Mn in } \mathrm{MnO_4^-} = +7Mn in MnO4−​=+7

The question says the change in oxidation state of manganese occurs by 3. So manganese must go from: +7→+4+7 \to +4+7→+4

This corresponds to formation of manganese dioxide: MnO4−→MnO2\mathrm{MnO_4^- \to MnO_2}MnO4−​→MnO2​

  1. Recall reduction products of permanganate in different media

Permanganate gives different products depending on the medium:

  • Acidic medium: MnO4−→Mn2+\mathrm{MnO_4^- \to Mn^{2+}}MnO4−​→Mn2+ Change in oxidation state: +7→+2(Δ=5)+7 \to +2 \quad (\Delta = 5)+7→+2(Δ=5)

  • Neutral or faintly alkaline medium: MnO4−→MnO2\mathrm{MnO_4^- \to MnO_2}MnO4−​→MnO2​ Change in oxidation state: +7→+4(Δ=3)+7 \to +4 \quad (\Delta = 3)+7→+4(Δ=3)

  • Strongly alkaline medium: MnO4−→MnO42−\mathrm{MnO_4^- \to MnO_4^{2-}}MnO4−​→MnO42−​ Change in oxidation state: +7→+6(Δ=1)+7 \to +6 \quad (\Delta = 1)+7→+6(Δ=1)

  1. Match with the condition in the question

Since the oxidation state change is 3, the reaction must occur in the medium where permanganate is reduced to MnO2\mathrm{MnO_2}MnO2​.

That happens in: neutral or faintly alkaline medium\text{neutral or faintly alkaline medium}neutral or faintly alkaline medium

  1. Check the options
  • A: aqueous neutral — correct, since neutral medium gives MnO2\mathrm{MnO_2}MnO2​.
  • B: both aqueous acidic and faintly alkaline — incorrect, acidic gives change of 5.
  • C: both aqueous acidic and neutral — incorrect, acidic again gives change of 5.
  • D: aqueous acidic — incorrect.
  1. Final answer

The medium that favours oxidation-state change of manganese by 3 is aqueous neutral.

So the correct option is: A\boxed{\text{A}}A​

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