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Coordination Compounds question

2025 · 2 Apr · Shift 1 · Q25
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Coordination Compounds question

2025 · 2 Apr · Shift 1 · Q25

JEE MainChemistryCoordination CompoundsNumerical+4 / −1
A transition metal (M) among Mn,Cr,Co\mathrm{Mn}, \mathrm{Cr}, \mathrm{Co}Mn,Cr,Co and Fe has the highest standard electrode potential (M3+/M2+)\left(\mathrm{M}^{3+} / \mathrm{M}^{2+}\right)(M3+/M2+). It forms a metal complex of the type [M(CN)6]4−\left[\mathrm{M}(\mathrm{CN})_6\right]^{4-}[M(CN)6​]4−. The number of electrons present in the eg\mathrm{e}_{\mathrm{g}}eg​ orbital of the complex is ‾\underline{\hspace{2cm}}​.
Numerical answer
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Correct answer: 1

  1. Identify the metal with highest E^(M^{3+}/M^{2+}) among Mn, Cr, Fe, Co

    The standard reduction potentials are approximately:

    Mn3++e−→Mn2+E∘≈+1.5 V\mathrm{Mn}^{3+} + e^- \to \mathrm{Mn}^{2+} \quad E^\circ \approx +1.5\,\text{V}Mn3++e−→Mn2+E∘≈+1.5V Co3++e−→Co2+E∘≈+1.82 V\mathrm{Co}^{3+} + e^- \to \mathrm{Co}^{2+} \quad E^\circ \approx +1.82\,\text{V}Co3++e−→Co2+E∘≈+1.82V Fe3++e−→Fe2+E∘≈+0.77 V\mathrm{Fe}^{3+} + e^- \to \mathrm{Fe}^{2+} \quad E^\circ \approx +0.77\,\text{V}Fe3++e−→Fe2+E∘≈+0.77V Cr3++e−→Cr2+E∘≈−0.41 V\mathrm{Cr}^{3+} + e^- \to \mathrm{Cr}^{2+} \quad E^\circ \approx -0.41\,\text{V}Cr3++e−→Cr2+E∘≈−0.41V

    Hence, the highest value is for Co.

  2. Write the complex

    Therefore the complex is:

    [Co(CN)6]4−[\mathrm{Co}(\mathrm{CN})_6]^{4-}[Co(CN)6​]4−
  3. Find oxidation state of Co

    Let oxidation state of Co be xxx.

    Since each CN−\mathrm{CN}^-CN− has charge −1-1−1:

    x+6(−1)=−4x + 6(-1) = -4x+6(−1)=−4 x−6=−4x - 6 = -4x−6=−4 x=+2x = +2x=+2

    So the metal ion is Co2+\mathrm{Co}^{2+}Co2+.

  4. Find d-electron configuration of Co2+\mathrm{Co}^{2+}Co2+

    Atomic number of Co = 27.

    Neutral Co:

    [Ar] 3d74s2[\mathrm{Ar}]\,3d^7 4s^2[Ar]3d74s2

    For Co2+\mathrm{Co}^{2+}Co2+, remove two electrons from 4s4s4s:

    [Ar] 3d7[\mathrm{Ar}]\,3d^7[Ar]3d7

    So it is a d7d^7d7 system.

  5. Use ligand strength of CN−\mathrm{CN}^-CN−

    CN−\mathrm{CN}^-CN− is a strong-field ligand, so the octahedral complex is low spin.

    Octahedral splitting:

    t2g lower,eg highert_{2g} \text{ lower}, \quad e_g \text{ higher}t2g​ lower,eg​ higher

    For low-spin d7d^7d7:

    t2g6eg1t_{2g}^6 e_g^1t2g6​eg1​
  6. Count electrons in ege_geg​

    From

    t2g6eg1t_{2g}^6 e_g^1t2g6​eg1​

    the number of electrons in ege_geg​ is:

    111

Final Answer: 1\boxed{1}1​

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