JEE MainChemistryCoordination CompoundsNumerical+4 / −1
A transition metal (M) among and Fe has the highest standard electrode potential . It forms a metal complex of the type . The number of electrons present in the orbital of the complex is .
Numerical answer
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Correct answer: 1
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Identify the metal with highest E^(M^{3+}/M^{2+}) among Mn, Cr, Fe, Co
The standard reduction potentials are approximately:
Hence, the highest value is for Co.
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Write the complex
Therefore the complex is:
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Find oxidation state of Co
Let oxidation state of Co be .
Since each has charge :
So the metal ion is .
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Find d-electron configuration of
Atomic number of Co = 27.
Neutral Co:
For , remove two electrons from :
So it is a system.
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Use ligand strength of
is a strong-field ligand, so the octahedral complex is low spin.
Octahedral splitting:
For low-spin :
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Count electrons in
From
the number of electrons in is:
Final Answer:
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