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Compounds Containing Nitrogen question

2024 · 30 Jan · Shift 1 · Q24
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  5. /2024 · 30 Jan · Shift 1 · Q24

Compounds Containing Nitrogen question

2024 · 30 Jan · Shift 1 · Q24

JEE MainChemistryCompounds Containing NitrogenNumerical+4 / −1
The compound formed by the reaction of ethanal with semicarbazide contains ‾\underline{\hspace{2cm}}​ number of nitrogen atoms.
Numerical answer
View written solutionFree

Correct answer: 3

  1. Identify the reaction

Ethanal is an aldehyde with formula: CH3CHO\text{CH}_3\text{CHO}CH3​CHO

Semicarbazide has the structure: NH2-NH-CO-NH2\text{NH}_2\text{-NH-CO-NH}_2NH2​-NH-CO-NH2​

Aldehydes react with semicarbazide to form semicarbazones.

  1. Write the reaction

The carbonyl group of ethanal reacts with semicarbazide with loss of one molecule of water: CH3CHO+H2N-NH-CO-NH2→CH3CH=N-NH-CO-NH2+H2O\text{CH}_3\text{CHO} + \text{H}_2\text{N-NH-CO-NH}_2 \rightarrow \text{CH}_3\text{CH=N-NH-CO-NH}_2 + \text{H}_2\text{O}CH3​CHO+H2​N-NH-CO-NH2​→CH3​CH=N-NH-CO-NH2​+H2​O

  1. Count the nitrogen atoms in the product

The product is ethanal semicarbazone: CH3CH=N-NH-CO-NH2\text{CH}_3\text{CH=N-NH-CO-NH}_2CH3​CH=N-NH-CO-NH2​

Nitrogen atoms present are:

  • one in CH=N\text{CH=N}CH=N
  • one in -NH-\text{-NH-}-NH-
  • one in -NH2\text{-NH}_2-NH2​

So total number of nitrogen atoms =3= 3=3.

  1. Final answer

The compound formed contains: 3\boxed{3}3​

  1. Comparison with stored answer

Stored correct answer = 333

My derived answer = 333

Hence, they agree.

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