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Compounds Containing Nitrogen question

2021 · 20 Jul · Shift 1 · Q17
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  5. /2021 · 20 Jul · Shift 1 · Q17

Compounds Containing Nitrogen question

2021 · 20 Jul · Shift 1 · Q17

JEE MainChemistryCompounds Containing NitrogenNumerical+4 / −1
The number of nitrogen atoms in a semicarbazone molecule of acetone is ‾\underline{\hspace{2cm}}​.
Numerical answer
View written solutionFree

Correct answer: 3

  1. Identify semicarbazone formation

A semicarbazone is formed when a carbonyl compound reacts with semicarbazide.

Semicarbazide has the structure: H2N−CO−NH−NH2\mathrm{H_2N-CO-NH-NH_2}H2​N−CO−NH−NH2​

It contains 3 nitrogen atoms.

  1. Reaction with acetone

Acetone is: (CH3)2CO\mathrm{(CH_3)_2CO}(CH3​)2​CO

On reaction with semicarbazide, it forms acetone semicarbazone: (CH3)2C=NNHCONH2\mathrm{(CH_3)_2C=NNHCONH_2}(CH3​)2​C=NNHCONH2​

  1. Count nitrogen atoms in the product

In (CH3)2C=NNHCONH2\mathrm{(CH_3)_2C=NNHCONH_2}(CH3​)2​C=NNHCONH2​ there are:

  • one nitrogen in =N−=N-=N−
  • one nitrogen in −NH−-NH-−NH−
  • one nitrogen in −NH2-NH_2−NH2​

So total nitrogen atoms =3= 3=3.

  1. Final answer

The number of nitrogen atoms in semicarbazone of acetone is: 3\boxed{3}3​

  1. Comparison with stored answer

Stored correct answer = 3, which matches the derived answer.

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