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Compounds Containing Nitrogen question

2021 · 22 Jul · Shift 2 · Q5
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  5. /2021 · 22 Jul · Shift 2 · Q5

Compounds Containing Nitrogen question

2021 · 22 Jul · Shift 2 · Q5

JEE MainChemistryCompounds Containing NitrogenMCQ+4 / −1
JEE Main 2021 (Online) 22th July Evening Shift Chemistry - Compounds Containing Nitrogen Question 135 English In the chemical reactions given above A and B respectively are :
  1. A
    H3PO2H_3PO_2H3​PO2​ and CH3CH2ClCH_3CH_2ClCH3​CH2​Cl
  2. B
    CH3CH2OHCH_3CH_2OHCH3​CH2​OH and H3PO2H_3PO_2H3​PO2​
  3. C
    H3PO2H_3PO_2H3​PO2​ and CH3CH2OHCH_3CH_2OHCH3​CH2​OH
  4. D
    CH3CH2ClCH_3CH_2ClCH3​CH2​Cl and H3PO2H_3PO_2H3​PO2​
View written solutionFree

Correct answer: A

The question says “In the chemical reactions given above A and B respectively are”, but the actual reaction scheme is missing from the prompt.

So, the compounds AAA and BBB cannot be derived uniquely from first principles unless we know the reactions referred to by “given above”.

However, we can still analyze the options chemically.

1. Identify the roles of the given reagents

The recurring substances in the options are:

  • H3PO2H_3PO_2H3​PO2​ = hypophosphorous acid
  • CH3CH2ClCH_3CH_2ClCH3​CH2​Cl = ethyl chloride
  • CH3CH2OHCH_3CH_2OHCH3​CH2​OH = ethanol

A very standard use of H3PO2H_3PO_2H3​PO2​ in organic chemistry is:

R−N2+→H3PO2R−HR-N_2^+ \xrightarrow{H_3PO_2} R-HR−N2+​H3​PO2​​R−H

That is, it reduces a diazonium salt to the corresponding hydrocarbon.

Also, ethanol and ethyl chloride commonly appear in diazotisation / substitution-based conversion chains, but without the actual reaction sequence, we cannot prove which one is AAA and which one is BBB.

2. Compare with the stored answer

The stored correct answer is A:

A=H3PO2,B=CH3CH2ClA = H_3PO_2, \quad B = CH_3CH_2ClA=H3​PO2​,B=CH3​CH2​Cl

This is chemically plausible in standard nitrogen-compound conversion problems, where:

  • one step uses H3PO2H_3PO_2H3​PO2​ to replace a diazonium group by hydrogen,
  • another step may involve formation/use of ethyl chloride.

3. Final conclusion

Because the reaction scheme is absent, the answer cannot be independently derived with certainty from the prompt alone. But based on the provided stored answer and the common chemistry of H3PO2H_3PO_2H3​PO2​, the most plausible option is:

Option A.

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