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Compounds Containing Nitrogen question

2020 · 7 Jan · Shift 1 · Q8
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Compounds Containing Nitrogen question

2020 · 7 Jan · Shift 1 · Q8

JEE MainChemistryCompounds Containing NitrogenMCQ+4 / −1
Consider the following reaction : JEE Main 2020 (Online) 7th January Morning Slot Chemistry - Compounds Containing Nitrogen Question 178 English The product 'X' is used :
  1. A
    as food grade colourant
  2. B
    in acid base titration as an indicatior.
  3. C
    in laboratory test for phenols
  4. D
    in protein estimation as an alternative to ninhydrin.
View written solutionFree

Correct answer: B

  1. Identify the reaction type

The question refers to formation of a product XXX from a nitrogen-containing aromatic compound. In this chapter, such questions commonly involve diazotisation of an aromatic amine followed by azo coupling, giving an azo dye/indicator.

A standard product formed in this way is methyl orange, obtained through:

  • diazotisation of sulphanilic acid, then
  • coupling with dimethylaniline.
  1. Recognize the product XXX

The product formed is an azo compound containing the −N=N−-N=N-−N=N− group. The well-known compound prepared this way and frequently asked in exams is methyl orange.

  1. Use of methyl orange

Methyl orange is widely used:

  • as an acid-base indicator in titrations.

So, if XXX is methyl orange, then its use is:

in acid-base titration as an indicator\boxed{\text{in acid-base titration as an indicator}}in acid-base titration as an indicator​

  1. Check the options
  • A: as food grade colourant
    Not correct for methyl orange.

  • B: in acid base titration as an indicator
    Correct.

  • C: in laboratory test for phenols
    Phenols are tested using reagents like neutral FeCl3\mathrm{FeCl_3}FeCl3​, not methyl orange.

  • D: in protein estimation as an alternative to ninhydrin
    Not correct.

  1. Final answer

Thus, the product XXX is used:

B: in acid base titration as an indicator\boxed{\text{B: in acid base titration as an indicator}}B: in acid base titration as an indicator​

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