- A

- B

- C

- D

View written solutionFree
Correct answer: C
-
Identify the reaction type
Benzene diazonium chloride undergoes azo coupling with activated aromatic compounds like phenols and naphthols.
Here, the coupling partner is 1-naphthol in alkaline medium.
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Effect of alkaline medium
In alkaline medium, -naphthol forms the naphthoxide ion, which is even more reactive toward electrophilic substitution:
The diazonium ion, , acts as the electrophile.
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Position of coupling in 1-naphthol
In -naphthol, azo coupling occurs predominantly at the 2-position (the position adjacent to the group), because this position is highly activated.
So the product formed is:
-
Nature of the product
The structure is an azo dye having the linkage:
with the group at the 2-position of -naphthol.
-
Match with the correct option
The option representing 2-(phenylazo)-1-naphthol is Option C.
Final Answer
The coupling product is 2-(phenylazo)-1-naphthol, so the correct option is C.
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