Sign in
12thPass logo
New chatPYQ LibraryDoubtsRank report
Sign in to see Recents

Your guest activity stays on this device

Sign in to save progress →
Sign in

Chemical Kinetics and Nuclear Chemistry question

2024 · 8 Apr · Shift 1 · Q22
Guest · filters and generic practice availableBrowsing as a guest · PYQ filters and generic practice are available. Sign in only for personalised features and saved progress.
  1. PYQ Library
  2. /JEE Main
  3. /Chemistry
  4. /Chemical Kinetics and Nuclear Chemistry
  5. /2024 · 8 Apr · Shift 1 · Q22

Chemical Kinetics and Nuclear Chemistry question

2024 · 8 Apr · Shift 1 · Q22

JEE MainChemistryChemical Kinetics and Nuclear ChemistryNumerical+4 / −1
Consider the following reaction A+B→C\mathrm{A}+\mathrm{B} \rightarrow \mathrm{C}A+B→C The time taken for A to become 1/4th 1 / 4^{\text {th }}1/4th  of its initial concentration is twice the time taken to become 1/21 / 21/2 of the same. Also, when the change of concentration of B is plotted against time, the resulting graph gives a straight line with a negative slope and a positive intercept on the concentration axis. The overall order of the reaction is ‾\underline{\hspace{2cm}}​.
Numerical answer
View written solutionFree

Correct answer: 1

  1. Use the information about reactant A

We are told that for reactant AAA:

  • time to become 12\dfrac{1}{2}21​ of initial concentration =t1/2= t_{1/2}=t1/2​
  • time to become 14\dfrac{1}{4}41​ of initial concentration =2t1/2= 2t_{1/2}=2t1/2​

Now, if a reaction is first order in AAA, then: [A]=[A]0e−kt[A]=[A]_0 e^{-kt}[A]=[A]0​e−kt so the half-life is constant: t1/2=ln⁡2kt_{1/2}=\frac{\ln 2}{k}t1/2​=kln2​

Then going from [A]0[A]_0[A]0​ to [A]04\dfrac{[A]_0}{4}4[A]0​​ means two half-lives, so t1/4=2t1/2t_{1/4}=2t_{1/2}t1/4​=2t1/2​ which matches the given condition.

Hence, the reaction is first order with respect to AAA.

So, order in A=1A = 1A=1.


  1. Use the information about reactant B

It is given that when concentration of BBB is plotted against time, the graph is a straight line with negative slope and positive intercept.

A straight-line decrease of concentration with time means: [B]=[B]0−kt[B]=[B]_0-kt[B]=[B]0​−kt This is the integrated rate law for a zero-order dependence.

Hence, the reaction is zero order with respect to BBB.

So, order in B=0B = 0B=0.


  1. Find the overall order

Overall order === sum of individual orders: n=1+0=1n = 1 + 0 = 1n=1+0=1


  1. Final answer

The overall order of the reaction is: 1\boxed{1}1​


  1. Comparison with stored correct answer

Stored correct answer = 111

Our derived answer also = 111

So, the answer agrees with the stored correct answer.

PreviousNext

More from Chemical Kinetics and Nuclear Chemistry

  • For a reaction AK1​​ BK2​​C If the rate of formation of B is set to be zero then the concentration of B is given by :2024 · MCQ
  • Given below are two statements : Statement I : The rate law for the reaction A+B→C is rate (r)=k[A]2[B]. When the concentration of both A and B is doubled, the reaction rate is increased "x"… Includes diagram2024 · Numerical
  • Consider the following first order gas phase reaction at constant temperature A(g)→2B( g)+C(g) If the total pressure of the gases is found to be 200 torr after 23 sec…2024 · Numerical
  • Consider the following data for the given reaction 2HI(g)​→H2( g)​+I2( g)​ The order of the reaction is ​. Includes diagram2024 · Numerical
  • Time required for completion of 99.9% of a First order reaction is ​ times of half life (t1/2​) of the reaction.2024 · Numerical
  • For a reaction taking place in three steps at same temperature, overall rate constant K= K3​K1​ K2​​. If Ea1​,Ea2​ and Ea3​ are 40, 50 and 60 kJ/mol…2024 · Numerical
  • The half-life of radioisotope bromine - 82 is 36 hours. The fraction which remains after one day is ​×10−2. (Given antilog 0.2006=1.587)2024 · Numerical
  • The rate of First order reaction is 0.04 mol L−1 s−1 at 10 minutes and 0.03 mol L−1 s−1 at 20 minutes after initiation. Half life of the reaction is ​…2024 · Numerical