Sign in
12thPass logo
New chatPYQ LibraryDoubtsRank report
Sign in to see Recents

Your guest activity stays on this device

Sign in to save progress →
Sign in

Chemical Kinetics and Nuclear Chemistry question

2024 · 6 Apr · Shift 2 · Q25
Guest · filters and generic practice availableBrowsing as a guest · PYQ filters and generic practice are available. Sign in only for personalised features and saved progress.
  1. PYQ Library
  2. /JEE Main
  3. /Chemistry
  4. /Chemical Kinetics and Nuclear Chemistry
  5. /2024 · 6 Apr · Shift 2 · Q25

Chemical Kinetics and Nuclear Chemistry question

2024 · 6 Apr · Shift 2 · Q25

JEE MainChemistryChemical Kinetics and Nuclear ChemistryNumerical+4 / −1
Consider the two different first order reactions given below A+B→C (Reaction 1) P→Q (Reaction 2) \begin{aligned} & \mathrm{A}+\mathrm{B} \rightarrow \mathrm{C} \text { (Reaction 1) } \\ & \mathrm{P} \rightarrow \mathrm{Q} \text { (Reaction 2) } \end{aligned}​A+B→C (Reaction 1) P→Q (Reaction 2) ​ The ratio of the half life of Reaction 1 : Reaction 2 is 5:25: 25:2 If t1t_1t1​ and t2t_2t2​ represent the time taken to complete 2/3rd 2 / 3^{\text {rd }}2/3rd  and 4/5th 4 / 5^{\text {th }}4/5th  of Reaction 1 and Reaction 2 , respectively, then the value of the ratio t1:t2t_1: t_2t1​:t2​ is ‾\underline{\hspace{2cm}}​×10−1\times 10^{-1}×10−1(nearest integer). [Given : log⁡10(3)=0.477\log _{10}(3)=0.477log10​(3)=0.477 and log⁡10(5)=0.699\log _{10}(5)=0.699log10​(5)=0.699]
Numerical answer
View written solutionFree

Correct answer: 17

  1. Use half-life relation for first order reactions

For a first order reaction, t1/2=0.693kt_{1/2} = \frac{0.693}{k}t1/2​=k0.693​ So, half-life is inversely proportional to rate constant: t1/2∝1kt_{1/2} \propto \frac{1}{k}t1/2​∝k1​

Given, t1/2(Reaction 1):t1/2(Reaction 2)=5:2t_{1/2}(\text{Reaction 1}) : t_{1/2}(\text{Reaction 2}) = 5:2t1/2​(Reaction 1):t1/2​(Reaction 2)=5:2 Hence, k1k2=t1/2,2t1/2,1=25−1?\frac{k_1}{k_2} = \frac{t_{1/2,2}}{t_{1/2,1}} = \frac{2}{5}^{-1}?k2​k1​​=t1/2,1​t1/2,2​​=52​−1? More carefully, 0.693/k10.693/k2=52\frac{0.693/k_1}{0.693/k_2} = \frac{5}{2}0.693/k2​0.693/k1​​=25​ k2k1=52\frac{k_2}{k_1} = \frac{5}{2}k1​k2​​=25​ k1k2=25\frac{k_1}{k_2} = \frac{2}{5}k2​k1​​=52​

So, k2=52k1k_2 = \frac{5}{2}k_1k2​=25​k1​


  1. Time for a given fraction to be completed in first order reaction

For a first order reaction, t=2.303klog⁡[A]0[A]t = \frac{2.303}{k} \log \frac{[A]_0}{[A]}t=k2.303​log[A][A]0​​

If fraction reacted is xxx, then fraction remaining is (1−x)(1-x)(1−x). Thus, t=2.303klog⁡11−xt = \frac{2.303}{k} \log \frac{1}{1-x}t=k2.303​log1−x1​


  1. Compute t1t_1t1​ for Reaction 1

Reaction 1 is completed to 23\frac{2}{3}32​. So fraction remaining is 1−23=131-\frac{2}{3} = \frac{1}{3}1−32​=31​

Therefore, t1=2.303k1log⁡3t_1 = \frac{2.303}{k_1} \log 3t1​=k1​2.303​log3

Given log⁡3=0.477\log 3 = 0.477log3=0.477, t1=2.303×0.477k1t_1 = \frac{2.303 \times 0.477}{k_1}t1​=k1​2.303×0.477​


  1. Compute t2t_2t2​ for Reaction 2

Reaction 2 is completed to 45\frac{4}{5}54​. So fraction remaining is 1−45=151-\frac{4}{5} = \frac{1}{5}1−54​=51​

Therefore, t2=2.303k2log⁡5t_2 = \frac{2.303}{k_2} \log 5t2​=k2​2.303​log5

Given log⁡5=0.699\log 5 = 0.699log5=0.699, t2=2.303×0.699k2t_2 = \frac{2.303 \times 0.699}{k_2}t2​=k2​2.303×0.699​


  1. Find the ratio t1:t2t_1:t_2t1​:t2​

t1t2=2.303log⁡3k12.303log⁡5k2\frac{t_1}{t_2} = \frac{\frac{2.303\log 3}{k_1}}{\frac{2.303\log 5}{k_2}}t2​t1​​=k2​2.303log5​k1​2.303log3​​

t1t2=log⁡3log⁡5⋅k2k1\frac{t_1}{t_2} = \frac{\log 3}{\log 5}\cdot\frac{k_2}{k_1}t2​t1​​=log5log3​⋅k1​k2​​

Using k2k1=52\frac{k_2}{k_1} = \frac{5}{2}k1​k2​​=25​ we get t1t2=0.4770.699×52\frac{t_1}{t_2} = \frac{0.477}{0.699}\times \frac{5}{2}t2​t1​​=0.6990.477​×25​

First, 0.4770.699≈0.6824\frac{0.477}{0.699} \approx 0.68240.6990.477​≈0.6824

Then, t1t2≈0.6824×2.5=1.706\frac{t_1}{t_2} \approx 0.6824 \times 2.5 = 1.706t2​t1​​≈0.6824×2.5=1.706

So, t1:t2≈1.706:1t_1:t_2 \approx 1.706:1t1​:t2​≈1.706:1

The question asks for the value in the form ‾×10−1\underline{\hspace{1cm}}\times 10^{-1}​×10−1

Now, 1.706=17.06×10−11.706 = 17.06 \times 10^{-1}1.706=17.06×10−1

Nearest integer =17= 17=17.


  1. Final Answer

t1:t2=17×10−1t_1:t_2 = 17 \times 10^{-1}t1​:t2​=17×10−1 So the required integer is 17\boxed{17}17​

PreviousNext

More from Chemical Kinetics and Nuclear Chemistry

  • Consider the following reaction A+B→C The time taken for A to become 1/4th  of its initial concentration is twice the time taken to become 1/2 of the same. Also, when the change…2024 · Numerical
  • For a reaction AK1​​ BK2​​C If the rate of formation of B is set to be zero then the concentration of B is given by :2024 · MCQ
  • Given below are two statements : Statement I : The rate law for the reaction A+B→C is rate (r)=k[A]2[B]. When the concentration of both A and B is doubled, the reaction rate is increased "x"… Includes diagram2024 · Numerical
  • Consider the following first order gas phase reaction at constant temperature A(g)→2B( g)+C(g) If the total pressure of the gases is found to be 200 torr after 23 sec…2024 · Numerical
  • Consider the following data for the given reaction 2HI(g)​→H2( g)​+I2( g)​ The order of the reaction is ​. Includes diagram2024 · Numerical
  • Time required for completion of 99.9% of a First order reaction is ​ times of half life (t1/2​) of the reaction.2024 · Numerical
  • For a reaction taking place in three steps at same temperature, overall rate constant K= K3​K1​ K2​​. If Ea1​,Ea2​ and Ea3​ are 40, 50 and 60 kJ/mol…2024 · Numerical
  • The half-life of radioisotope bromine - 82 is 36 hours. The fraction which remains after one day is ​×10−2. (Given antilog 0.2006=1.587)2024 · Numerical