JEE MainChemistryChemical Kinetics and Nuclear ChemistryNumerical+4 / −1
Consider the two different first order reactions given below The ratio of the half life of Reaction 1 : Reaction 2 is If and represent the time taken to complete and of Reaction 1 and Reaction 2 , respectively, then the value of the ratio is (nearest integer). [Given : and ]
Numerical answer
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Correct answer: 17
- Use half-life relation for first order reactions
For a first order reaction, So, half-life is inversely proportional to rate constant:
Given, Hence, More carefully,
So,
- Time for a given fraction to be completed in first order reaction
For a first order reaction,
If fraction reacted is , then fraction remaining is . Thus,
- Compute for Reaction 1
Reaction 1 is completed to . So fraction remaining is
Therefore,
Given ,
- Compute for Reaction 2
Reaction 2 is completed to . So fraction remaining is
Therefore,
Given ,
- Find the ratio
Using we get
First,
Then,
So,
The question asks for the value in the form
Now,
Nearest integer .
- Final Answer
So the required integer is
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