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Chemical Kinetics and Nuclear Chemistry question

2007 · Shift 0 · Q24
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Chemical Kinetics and Nuclear Chemistry question

2007 · Shift 0 · Q24

JEE MainChemistryChemical Kinetics and Nuclear ChemistryMCQ+4 / −1
A radioactive element gets spilled over the floor of a room. Its half-life period is 30 days. If the initial activity is ten times the permissible value, after how many days will it be safe to enter the room?
  1. A
    1000 days
  2. B
    300 days
  3. C
    10 days
  4. D
    100 days
View written solutionFree

Correct answer: D

  1. Use radioactive decay law for activity

    Activity decays in the same way as the number of undecayed nuclei: A=A0(12)t/T1/2A = A_0\left(\frac{1}{2}\right)^{t/T_{1/2}}A=A0​(21​)t/T1/2​ where:

    • A0A_0A0​ = initial activity
    • AAA = activity after time ttt
    • T1/2=30T_{1/2} = 30T1/2​=30 days
  2. Interpret the safety condition

    Initially, the activity is 10 times the permissible value.

    Let the permissible activity be ApA_pAp​. Then initially, A0=10ApA_0 = 10A_pA0​=10Ap​

    The room becomes safe when: A=ApA = A_pA=Ap​

  3. Substitute into the decay equation

    Ap=10Ap(12)t/30A_p = 10A_p\left(\frac{1}{2}\right)^{t/30}Ap​=10Ap​(21​)t/30

    Cancel ApA_pAp​ from both sides: 1=10(12)t/301 = 10\left(\frac{1}{2}\right)^{t/30}1=10(21​)t/30

    So, (12)t/30=110\left(\frac{1}{2}\right)^{t/30} = \frac{1}{10}(21​)t/30=101​

  4. Solve for ttt

    Taking logarithms: t30log⁡(12)=log⁡(110)\frac{t}{30}\log\left(\frac{1}{2}\right) = \log\left(\frac{1}{10}\right)30t​log(21​)=log(101​)

    Hence, t30=log⁡(1/10)log⁡(1/2)=log⁡10log⁡2≈10.3010≈3.32\frac{t}{30} = \frac{\log(1/10)}{\log(1/2)} = \frac{\log 10}{\log 2} \approx \frac{1}{0.3010} \approx 3.3230t​=log(1/2)log(1/10)​=log2log10​≈0.30101​≈3.32

    Therefore, t≈30×3.32=99.6 dayst \approx 30 \times 3.32 = 99.6 \text{ days}t≈30×3.32=99.6 days

    So the required time is approximately: t≈100 dayst \approx 100 \text{ days}t≈100 days

  5. Check options

    • A: 100010001000 days — too large
    • B: 300300300 days — too large
    • C: 101010 days — too small
    • D: 100100100 days — correct

Final Answer: Option D

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