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Chemical Kinetics and Nuclear Chemistry question

2006 · Shift 0 · Q35
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Chemical Kinetics and Nuclear Chemistry question

2006 · Shift 0 · Q35

JEE MainChemistryChemical Kinetics and Nuclear ChemistryMCQ+4 / −1
In the transformation of 92238U{}_{92}^{238}U92238​U to 92234U{}_{92}^{234}U92234​U, if one emission is an α-particle, what should be the other emission(s)?
  1. A
    Two β−\beta^-β−
  2. B
    Two β−\beta^-β− and one β+\beta^+β+
  3. C
    One β−\beta^-β− and one γ\gammaγ
  4. D
    One β+\beta^+β+ and One β−\beta^-β−
View written solutionFree

Correct answer: A

  1. Write the initial and final nuclei

    Initial nucleus: 92238U{}_{92}^{238}U92238​U

    Final nucleus: 92234U{}_{92}^{234}U92234​U

  2. Effect of one α\alphaα-particle emission

    An α\alphaα-particle is: 24α{}_2^4\alpha24​α

    So after one α\alphaα emission:

    • Mass number decreases by 444
    • Atomic number decreases by 222

    Therefore, 92238U→α90234Th{}_{92}^{238}U \xrightarrow{\alpha} {}_{90}^{234}Th92238​Uα​90234​Th

  3. Compare with required final nucleus

    After α\alphaα emission we have: 90234Th{}_{90}^{234}Th90234​Th

    But required final nucleus is: 92234U{}_{92}^{234}U92234​U

    So now:

    • Mass number is already correct: 234234234
    • Atomic number must increase from 909090 to 929292
  4. Which emission increases atomic number by 1 without changing mass number?

    In β−\beta^-β− emission: n→p+e−+νˉn \to p + e^- + \bar{\nu}n→p+e−+νˉ

    Hence:

    • Atomic number increases by 111
    • Mass number remains unchanged

    Therefore, to increase atomic number from 909090 to 929292, we need two β−\beta^-β− emissions.

  5. Check the full sequence

    92238U→α90234Th{}_{92}^{238}U \xrightarrow{\alpha} {}_{90}^{234}Th92238​Uα​90234​Th 90234Th→β−91234Pa{}_{90}^{234}Th \xrightarrow{\beta^-} {}_{91}^{234}Pa90234​Thβ−​91234​Pa 91234Pa→β−92234U{}_{91}^{234}Pa \xrightarrow{\beta^-} {}_{92}^{234}U91234​Paβ−​92234​U

    Net result: 92238U→92234U+α+2β−{}_{92}^{238}U \to {}_{92}^{234}U + \alpha + 2\beta^-92238​U→92234​U+α+2β−

  6. Evaluate options

    • A: Two β−\beta^-β− — Correct
    • B: Two β−\beta^-β− and one β+\beta^+β+ — β+\beta^+β+ lowers atomic number by 111, so incorrect
    • C: One β−\beta^-β− and one γ\gammaγ — γ\gammaγ does not change atomic number; net increase only 111, so incorrect
    • D: One β+\beta^+β+ and one β−\beta^-β− — net change in atomic number is 000, so incorrect
  7. Final answer

    The other emissions should be: Two β−\boxed{\text{Two } \beta^-}Two β−​

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