JEE MainChemistryChemical EquilibriumNumerical+4 / −1
A homogeneous ideal gaseous reaction is carried out in a 25 litre flask at 27 C. The initial amount of was 1 mole and the equilibrium pressure was 1.9 atm. The value of Kp is x 10 2. The value of x is . (Integer answer) [R = 0.08206 dm3atm K 1mol 1]
Numerical answer
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Correct answer: 72TO75
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Let the degree of dissociation be .
Reaction:
Initially, moles are:
At equilibrium:
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Total moles at equilibrium:
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Use the ideal gas equation to find total moles at equilibrium: Given:
So,
Therefore,
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Find mole fractions:
Partial pressures:
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Write the expression for :
Substitute partial pressures:
Simplifying,
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Substitute and :
First,
Thus,
Numerator:
Denominator:
Hence,
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Since ,
Therefore,
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Final integer answer:
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Comparison with stored answer: The stored correct answer is
72TO75, which includes . So the derived answer agrees with the stored answer range.
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