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Chemical Equilibrium question

2019 · 10 Apr · Shift 2 · Q10
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Chemical Equilibrium question

2019 · 10 Apr · Shift 2 · Q10

JEE MainChemistryChemical EquilibriumMCQ+4 / −1
For the reaction, 2SO2SO_2SO2​(g) + O2O_2O2​(g) = 2SO3SO_3SO3​(g), Δ\DeltaΔ H = –57.2 kJ mol–1 and KC = 1.7 × 1016 Which of the following statement is incorrect ?
  1. A
    The equilibrium will shift in forward direction as the pressure increase.
  2. B
    The addition of inert gas at constant volume will be not affect the equilibrium constant.
  3. C
    The equilibrium constant is large suggestive of reaction going to completion and so no catalyst is required.
  4. D
    The equilibrium constant decreases as the temperature increase.
View written solutionFree

Correct answer: C

  1. Given reaction

2SO2(g)+O2(g)⇌2SO3(g),ΔH=−57.2 kJ mol−12SO_2(g) + O_2(g) \rightleftharpoons 2SO_3(g), \qquad \Delta H = -57.2\,\text{kJ mol}^{-1}2SO2​(g)+O2​(g)⇌2SO3​(g),ΔH=−57.2kJ mol−1

Since ΔH<0\Delta H < 0ΔH<0, the reaction is exothermic.

Also,

Kc=1.7×1016K_c = 1.7 \times 10^{16}Kc​=1.7×1016

This is a very large equilibrium constant, so equilibrium strongly favors products.


  1. Check option A

Reaction has:

  • Reactant moles of gas =2+1=3= 2+1=3=2+1=3
  • Product moles of gas =2=2=2

Increase in pressure shifts equilibrium toward the side with fewer moles of gas.

So equilibrium shifts forward (towards SO3SO_3SO3​).

✅ Option A is correct.


  1. Check option B

Adding an inert gas at constant volume does not change the partial pressures of reacting gases because

pi=niRTVp_i = \frac{n_iRT}{V}pi​=Vni​RT​

and ni,T,Vn_i, T, Vni​,T,V for reacting gases remain unchanged.

Also, equilibrium constant depends only on temperature, not on addition of inert gas.

✅ Option B is correct.


  1. Check option C

A very large KcK_cKc​ means products are highly favored at equilibrium, i.e. reaction is thermodynamically favorable.

But catalyst does not change equilibrium position or equilibrium constant. It only speeds up the rate at which equilibrium is attained.

So even if reaction is favorable, a catalyst may still be required to make the reaction proceed fast enough in practice.

Hence the statement

"The equilibrium constant is large suggestive of reaction going to completion and so no catalyst is required"

is incorrect.

❌ Option C is incorrect.


  1. Check option D

For an exothermic reaction, increasing temperature shifts equilibrium in the backward direction. Thus equilibrium constant decreases with increase in temperature.

From van't Hoff relation:

d(ln⁡K)dT=ΔHRT2\frac{d(\ln K)}{dT} = \frac{\Delta H}{RT^2}dTd(lnK)​=RT2ΔH​

Since ΔH<0\Delta H < 0ΔH<0, this derivative is negative, so KKK decreases as TTT increases.

✅ Option D is correct.


  1. Final conclusion

The incorrect statement is:

C\boxed{\text{C}}C​

This matches the stored correct answer.

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