- AThe equilibrium will shift in forward direction as the pressure increase.
- BThe addition of inert gas at constant volume will be not affect the equilibrium constant.
- CThe equilibrium constant is large suggestive of reaction going to completion and so no catalyst is required.
- DThe equilibrium constant decreases as the temperature increase.
View written solutionFree
Correct answer: C
- Given reaction
Since , the reaction is exothermic.
Also,
This is a very large equilibrium constant, so equilibrium strongly favors products.
- Check option A
Reaction has:
- Reactant moles of gas
- Product moles of gas
Increase in pressure shifts equilibrium toward the side with fewer moles of gas.
So equilibrium shifts forward (towards ).
✅ Option A is correct.
- Check option B
Adding an inert gas at constant volume does not change the partial pressures of reacting gases because
and for reacting gases remain unchanged.
Also, equilibrium constant depends only on temperature, not on addition of inert gas.
✅ Option B is correct.
- Check option C
A very large means products are highly favored at equilibrium, i.e. reaction is thermodynamically favorable.
But catalyst does not change equilibrium position or equilibrium constant. It only speeds up the rate at which equilibrium is attained.
So even if reaction is favorable, a catalyst may still be required to make the reaction proceed fast enough in practice.
Hence the statement
"The equilibrium constant is large suggestive of reaction going to completion and so no catalyst is required"
is incorrect.
❌ Option C is incorrect.
- Check option D
For an exothermic reaction, increasing temperature shifts equilibrium in the backward direction. Thus equilibrium constant decreases with increase in temperature.
From van't Hoff relation:
Since , this derivative is negative, so decreases as increases.
✅ Option D is correct.
- Final conclusion
The incorrect statement is:
This matches the stored correct answer.
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