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Chemical Equilibrium question

2019 · 12 Jan · Shift 1 · Q1
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Chemical Equilibrium question

2019 · 12 Jan · Shift 1 · Q1

JEE MainChemistryChemical EquilibriumMCQ+4 / −1
Two solids dissociate as follows – JEE Main 2019 (Online) 12th January Morning Slot Chemistry - Chemical Equilibrium Question 78 English The total pressure when both the solids dissociated simultaneously is -
  1. A
    (x + y) atm
  2. B
    (x+y)\left( {\sqrt {x + y} } \right)(x+y​) atm
  3. C
    2 (x+y)\left( {\sqrt {x + y} } \right)(x+y​) atm
  4. D
    x2 + y2 atm
View written solutionFree

Correct answer: C

Let the two solid dissociations be of the standard type:

A(s)⇌B(s)+C(g)A(s) \rightleftharpoons B(s) + C(g)A(s)⇌B(s)+C(g) with equilibrium pressure xxx atm, and

P(s)⇌Q(s)+R(g)P(s) \rightleftharpoons Q(s) + R(g)P(s)⇌Q(s)+R(g) with equilibrium pressure yyy atm.

Since only solids and gases are involved, the equilibrium constants depend only on gaseous pressures.


1. Meaning of the given pressures xxx and yyy

For the first dissociation:

A(s)⇌B(s)+C(g)A(s) \rightleftharpoons B(s) + C(g)A(s)⇌B(s)+C(g)

If its equilibrium pressure is xxx atm, then

Kp1=pC=xK_{p1} = p_C = xKp1​=pC​=x

Similarly, for the second dissociation:

P(s)⇌Q(s)+R(g)P(s) \rightleftharpoons Q(s) + R(g)P(s)⇌Q(s)+R(g)

Kp2=pR=yK_{p2} = p_R = yKp2​=pR​=y


2. When both solids dissociate simultaneously

When both are present together, each solid establishes its own equilibrium independently because solids have unit activity.

Thus at equilibrium:

pC=x,pR=yp_C = x, \qquad p_R = ypC​=x,pR​=y

Hence total pressure should be

Ptotal=pC+pR=x+yP_{\text{total}} = p_C + p_R = x + yPtotal​=pC​+pR​=x+y


3. Checking options

  • A: (x+y)(x+y)(x+y) atm ✅
  • B: x+y\sqrt{x+y}x+y​ atm ❌
  • C: 2x+y2\sqrt{x+y}2x+y​ atm ❌
  • D: x2+y2x^2+y^2x2+y2 atm ❌

So the correct answer is:

x+y atm\boxed{x+y\text{ atm}}x+y atm​


4. Comparison with stored answer

Stored correct answer = C

My derived answer = A

These do not match.

The stored answer would be correct only for a different type of dissociation, such as when each solid produces two moles of gaseous products and the given x,yx,yx,y were related differently to KpK_pKp​. But for the usual interpretation of independent solid dissociations giving one gaseous species each, total pressure is simply the sum of their equilibrium partial pressures.

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