The total pressure when both the solids dissociated simultaneously is -- A(x + y) atm
- Batm
- C2 atm
- Dx2 + y2 atm
View written solutionFree
Correct answer: C
Let the two solid dissociations be of the standard type:
with equilibrium pressure atm, and
with equilibrium pressure atm.
Since only solids and gases are involved, the equilibrium constants depend only on gaseous pressures.
1. Meaning of the given pressures and
For the first dissociation:
If its equilibrium pressure is atm, then
Similarly, for the second dissociation:
2. When both solids dissociate simultaneously
When both are present together, each solid establishes its own equilibrium independently because solids have unit activity.
Thus at equilibrium:
Hence total pressure should be
3. Checking options
- A: atm ✅
- B: atm ❌
- C: atm ❌
- D: atm ❌
So the correct answer is:
4. Comparison with stored answer
Stored correct answer = C
My derived answer = A
These do not match.
The stored answer would be correct only for a different type of dissociation, such as when each solid produces two moles of gaseous products and the given were related differently to . But for the usual interpretation of independent solid dissociations giving one gaseous species each, total pressure is simply the sum of their equilibrium partial pressures.
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