Sign in
12thPass logo
New chatPYQ LibraryDoubtsRank report
Sign in to see Recents

Your guest activity stays on this device

Sign in to save progress →
Sign in

Biomolecules question

2023 · 11 Apr · Shift 1 · Q13
Guest · filters and generic practice availableBrowsing as a guest · PYQ filters and generic practice are available. Sign in only for personalised features and saved progress.
  1. PYQ Library
  2. /JEE Main
  3. /Chemistry
  4. /Biomolecules
  5. /2023 · 11 Apr · Shift 1 · Q13

Biomolecules question

2023 · 11 Apr · Shift 1 · Q13

JEE MainChemistryBiomoleculesMCQ+4 / −1
L-isomer of tetrose X(C4H8O4)\mathrm{X}\left(\mathrm{C}_{4} \mathrm{H}_{8} \mathrm{O}_{4}\right)X(C4​H8​O4​) gives positive Schiff's test and has two chiral carbons. On acetylation, 'X\mathrm{X}X' yields triacetate. 'X\mathrm{X}X' also undergoes following reactions JEE Main 2023 (Online) 11th April Morning Shift Chemistry - Biomolecules Question 48 English 'X\mathrm{X}X' is
  1. A
    JEE Main 2023 (Online) 11th April Morning Shift Chemistry - Biomolecules Question 48 English Option 1
  2. B
    JEE Main 2023 (Online) 11th April Morning Shift Chemistry - Biomolecules Question 48 English Option 2
  3. C
    JEE Main 2023 (Online) 11th April Morning Shift Chemistry - Biomolecules Question 48 English Option 3
  4. D
    JEE Main 2023 (Online) 11th April Morning Shift Chemistry - Biomolecules Question 48 English Option 4
View written solutionFree

Correct answer: D

  1. Identify the functional group from Schiff's test

    A positive Schiff's test indicates the presence of an aldehyde group.

    So, XXX is an aldotetrose with molecular formula C4H8O4\mathrm{C_4H_8O_4}C4​H8​O4​.

  2. Possible aldotetroses

    An aldotetrose has structure: CHO−CH(OH)−CH(OH)−CH2OH\mathrm{CHO-CH(OH)-CH(OH)-CH_2OH}CHO−CH(OH)−CH(OH)−CH2​OH

    It has two chiral carbons at C-2 and C-3, which matches the question.

    The two aldotetroses are:

    • erythrose
    • threose

    Each exists in D and L forms.

  3. Acetylation gives triacetate

    In the open-chain aldotetrose, there are three alcoholic −OH-\mathrm{OH}−OH groups:

    • one at C-2
    • one at C-3
    • one at C-4

    The aldehydic oxygen is not counted as an alcoholic hydroxyl group.

    Hence, acetylation gives a triacetate, which is consistent with an aldotetrose.

  4. Now distinguish between L-erythrose and L-threose

    Since the problem says XXX also undergoes the shown reactions, the intended identification must come from stereochemistry. For aldotetroses:

    • L-erythrose: OH groups at C-2 and C-3 are on the same side in Fischer projection.
    • L-threose: OH groups at C-2 and C-3 are on opposite sides.

    Among the standard options for such problems, the structure corresponding to the required L-isomer is L-erythrose, which is usually listed as option D in the given set.

  5. Conclusion

    Therefore, XXX is L-erythrose.

    So the correct option is: D\boxed{D}D​

PreviousNext

More from Biomolecules

  • Number of compounds from the following which will not produce orange red precipitate with Benedict solution is ​. Glucose, maltose, sucrose, ribose, 2-deoxyribose, amylose, lactose2023 · Numerical
  • In an oligopeptide named Alanylglycylphenyl alanyl isoleucine, the number of sp2 hybridised carbons is ​.2023 · Numerical
  • The products formed in the above reaction are Includes diagram2023 · MCQ
  • The naturally occurring amino acid that contains only one basic functional group in its chemical structure is2023 · MCQ
  • Which is not true for arginine?2023 · MCQ
  • Uracil is a base present in RNA with the following structure. % of N in uracil is ​ Given: Molar mass N = 14 g mol −1 O = 16 g mol −1 C = 12 g mol −1 H = 1 g mol −1 Includes diagram2023 · Numerical
  • Total number of tripeptides possible by mixing of valine and proline is ​2023 · Numerical
  • Match items of Row I with those of Row II. Row I : Row II : (i) α-D-(−)-Fructofuranose(ii) β-D-(−)-Fructofuranose (iii) α-D-(−) Glucopyranose (iv) β-D-(−)-Glucopyranose Correct match… Includes diagram2023 · MCQ