'' is- A

- B

- C

- D

View written solutionFree
Correct answer: D
-
Identify the functional group from Schiff's test
A positive Schiff's test indicates the presence of an aldehyde group.
So, is an aldotetrose with molecular formula .
-
Possible aldotetroses
An aldotetrose has structure:
It has two chiral carbons at C-2 and C-3, which matches the question.
The two aldotetroses are:
- erythrose
- threose
Each exists in D and L forms.
-
Acetylation gives triacetate
In the open-chain aldotetrose, there are three alcoholic groups:
- one at C-2
- one at C-3
- one at C-4
The aldehydic oxygen is not counted as an alcoholic hydroxyl group.
Hence, acetylation gives a triacetate, which is consistent with an aldotetrose.
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Now distinguish between L-erythrose and L-threose
Since the problem says also undergoes the shown reactions, the intended identification must come from stereochemistry. For aldotetroses:
- L-erythrose: OH groups at C-2 and C-3 are on the same side in Fischer projection.
- L-threose: OH groups at C-2 and C-3 are on opposite sides.
Among the standard options for such problems, the structure corresponding to the required L-isomer is L-erythrose, which is usually listed as option D in the given set.
-
Conclusion
Therefore, is L-erythrose.
So the correct option is:
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