JEE MainChemistryBasics of Organic ChemistryMCQ+4 / −1
Identify correct statement/s : (A) and are activating group. (B) and -OH are meta directing group. (C) -CN and are meta directing group. (D) Activating groups act as ortho - and para directing groups. (E) Halides are activating groups. Choose the correct answer from the options given below :
- Aand (D) only
- Band only
- C(A) and (C) only
- D(A) only
View written solutionFree
Correct answer: A
-
Recall the directing and activating/deactivating effects in electrophilic aromatic substitution
- Activating groups donate electron density to the benzene ring and generally direct incoming electrophiles to the ortho and para positions.
- Deactivating groups withdraw electron density and are generally meta directors.
- Exception: Halogens are deactivating but ortho/para directing.
-
Check each statement
(A) and are activating group.
- donates electron density by resonance: activating.
- (acetamido) also donates by resonance from nitrogen lone pair: activating.
Hence, (A) is correct.
(B) and are meta directing group.
- is electron withdrawing, so it is meta directing.
- But is strongly activating and ortho/para directing, not meta directing.
Hence, (B) is incorrect.
(C) and are meta directing group.
- is a meta director.
- is strongly electron withdrawing and also meta directing.
Hence, (C) is correct.
(D) Activating groups act as ortho- and para-directing groups.
- This is the standard rule for electrophilic aromatic substitution.
Hence, (D) is correct.
(E) Halides are activating groups.
- Halogens are deactivating due to strong effect, though they are ortho/para directing because of resonance.
Hence, (E) is incorrect.
-
Collect correct statements
Correct statements are:
-
Match with options
- Option A: and only ✅
- Option B: includes wrong statements and ❌
- Option C: misses ❌
- Option D: incomplete ❌
Therefore, the correct option is A.
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