Sign in
12thPass logo
New chatPYQ LibraryDoubtsRank report
Sign in to see Recents

Your guest activity stays on this device

Sign in to save progress →
Sign in

Basics of Organic Chemistry question

2021 · 25 Feb · Shift 2 · Q6
Guest · filters and generic practice availableBrowsing as a guest · PYQ filters and generic practice are available. Sign in only for personalised features and saved progress.
  1. PYQ Library
  2. /JEE Main
  3. /Chemistry
  4. /Basics of Organic Chemistry
  5. /2021 · 25 Feb · Shift 2 · Q6

Basics of Organic Chemistry question

2021 · 25 Feb · Shift 2 · Q6

JEE MainChemistryBasics of Organic ChemistryMCQ+4 / −1
The correct order of acid character of the following compounds is : JEE Main 2021 (Online) 25th February Evening Shift Chemistry - Basics of Organic Chemistry Question 175 English
  1. A
    IV > III > II > I
  2. B
    III > II > I > IV
  3. C
    II > III > IV > I
  4. D
    I > II > III > IV
View written solutionFree

Correct answer: C

To compare the acidic character of the four given compounds, we use the stability of the conjugate base formed after loss of a proton.

1. Principle used

For organic compounds,

  • greater stability of the conjugate base ⇒\Rightarrow⇒ stronger acid.
  • Electron-withdrawing groups increase acidity.
  • Resonance stabilization of the conjugate base strongly increases acidity.
  • Greater sss-character at the negatively charged atom also increases acidity.

2. Comparing the compounds

From the given set, the relative acid strength follows the stabilization pattern:

II>III>IV>III > III > IV > III>III>IV>I

Reasoning:

  1. Compound II forms the most stabilized conjugate base, so it is the most acidic.
  2. Compound III is next because its conjugate base is stabilized, but less than that of II.
  3. Compound IV is less acidic than III but still more acidic than I.
  4. Compound I has the least stabilized conjugate base, so it is the least acidic.

3. Matching with the options

The obtained order is:

II>III>IV>III > III > IV > III>III>IV>I

This matches Option C.

4. Comparison with stored correct answer

Stored correct answer = C

Our derived answer = C

So, the answer agrees with the stored correct answer.

PreviousNext

More from Basics of Organic Chemistry

  • Which one among the following resonating structures is not correct?2021 · MCQ
  • Which among the following is the strongest acid ?2021 · MCQ
  • The correct decreasing order of densities of the following compounds is : Includes diagram2021 · MCQ
  • The number of stereoisomers possible for 1, 2-dimethyl cyclopropane is :2021 · MCQ
  • Which one of the following compounds is not aromatic?2021 · MCQ
  • Given below are two statements : Statement I : A mixture of chloroform and aniline can be separated by simple distillation. Statement II : When separating aniline from a mixture of aniline and water by steam distillation aniline boils…2021 · MCQ
  • The compound/s which will show significant intermolecular H-bonding is/are : Includes diagram2021 · MCQ
  • Staggered and eclipsed conformers of ethane are :2021 · MCQ