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Basics of Organic Chemistry question

2021 · 27 Jul · Shift 1 · Q11
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Basics of Organic Chemistry question

2021 · 27 Jul · Shift 1 · Q11

JEE MainChemistryBasics of Organic ChemistryMCQ+4 / −1
Staggered and eclipsed conformers of ethane are :
  1. A
    Polymers
  2. B
    Rotamers
  3. C
    Enantiomers
  4. D
    Mirror images
View written solutionFree

Correct answer: B

  1. Understand the terms

    Ethane, C2H6\mathrm{C_2H_6}C2​H6​, has a single bond between the two carbon atoms.

    Because a C−C\mathrm{C-C}C−C single bond allows free rotation, different spatial arrangements of the hydrogen atoms are possible.

  2. Staggered and eclipsed forms

    The two important conformations of ethane are:

    • Staggered conformation
    • Eclipsed conformation

    These forms arise due to rotation about the C−C\mathrm{C-C}C−C single bond.

  3. What are such conformations called?

    Conformations obtained by rotation around a single bond are called rotamers (or conformers).

    Therefore, staggered and eclipsed conformers of ethane are rotamers.

  4. Check options

    • A: Polymers →\rightarrow→ Incorrect. These are large molecules made by repeating units.
    • B: Rotamers →\rightarrow→ Correct.
    • C: Enantiomers →\rightarrow→ Incorrect. Enantiomers are non-superimposable mirror images.
    • D: Mirror images →\rightarrow→ Incorrect. Staggered and eclipsed forms are not mirror images; they are rotational conformations.
  5. Final answer

    B: Rotamers\boxed{\text{B: Rotamers}}B: Rotamers​

  6. Comparison with stored correct answer

    Stored correct answer = B

    Derived answer = B

    Hence, the derived answer agrees with the stored correct answer.

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