- ALactic acid
- B2-Pentanone
- CPheno
- D2- Butene
View written solutionFree
Correct answer: B
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Recall the condition for tautomerism
Tautomerism, especially keto-enol tautomerism, is shown by compounds having:
- a carbonyl group , and
- at least one -hydrogen on the carbon adjacent to the carbonyl carbon.
Then the equilibrium is:
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Check each option
A: Lactic acid
Lactic acid is . It contains a carboxylic acid group, not a simple aldehyde/ketone system suitable for normal keto-enol tautomerism in this context. Hence, it is not typically considered to exhibit tautomerism here.
B: 2-Pentanone
Structure: It is a ketone and has -hydrogens on both sides of the carbonyl group. Therefore, it shows keto-enol tautomerism.
Example: So, this compound exhibits tautomerism.
C: Phenol
Phenol mainly exists as . Although special valence tautomeric forms may be discussed in advanced contexts, it is not the standard answer for simple tautomerism questions of this type. So, not correct here.
D: 2-Butene
Structure: This is an alkene and does not have the required carbonyl--hydrogen arrangement. Hence, it does not show keto-enol tautomerism.
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Conclusion
The compound that exhibits tautomerism is:
-
Comparison with stored correct answer
Stored correct answer: B
Derived answer: B
These match.
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