- A2
- B4
- C6
- D3
View written solutionFree
Correct answer: B
- Write the structure clearly
The compound is:
This is a five-carbon chain with:
- one double bond between C-2 and C-3,
- one hydroxyl group on C-4.
So the structure is pent-2-en-4-ol.
- Check for geometrical isomerism about the double bond
The double bond is between C-2 and C-3:
For geometrical isomerism, each carbon of the double bond must have two different groups.
- On C-2: groups are and H
- On C-3: groups are and H
Since each double-bond carbon has two different substituents, E/Z (cis/trans) isomerism is possible.
Hence, number of geometrical isomers = .
- Check for optical isomerism
Now inspect the carbon bearing OH:
That carbon is attached to:
- H
These are four different groups, so this carbon is a chiral center.
Thus, for each geometrical isomer, there are 2 optical isomers (an enantiomeric pair).
Hence, number of optical possibilities per geometrical form = .
- Total number of stereoisomers
Total stereoisomers:
- Check for meso form
A meso form would require at least two stereocenters and internal symmetry. Here there is only one chiral center, so no meso form exists.
- Final answer
The number of stereoisomers is:
So the correct option is B.
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