Sign in
12thPass logo
New chatPYQ LibraryDoubtsRank report
Sign in to see Recents

Your guest activity stays on this device

Sign in to save progress →
Sign in

Basics of Organic Chemistry question

2008 · Shift 0 · Q13
Guest · filters and generic practice availableBrowsing as a guest · PYQ filters and generic practice are available. Sign in only for personalised features and saved progress.
  1. PYQ Library
  2. /JEE Main
  3. /Chemistry
  4. /Basics of Organic Chemistry
  5. /2008 · Shift 0 · Q13

Basics of Organic Chemistry question

2008 · Shift 0 · Q13

JEE MainChemistryBasics of Organic ChemistryMCQ+4 / −1
The absolute configuration of AIEEE 2008 Chemistry - Basics of Organic Chemistry Question 227 English
  1. A
    S,SS,SS,S
  2. B
    R,RR,RR,R
  3. C
    R,SR,SR,S
  4. D
    S,RS,RS,R
View written solutionFree

Correct answer: QUESTION INCOMPLETE: STRUCTURE MISSING, SO ABSOLUTE CONFIGURATION CANNOT BE ASSIGNED

The question as provided is incomplete: it says “The absolute configuration of” but the actual structure/molecule is missing.

To determine an absolute configuration such as R,RR,RR,R, S,SS,SS,S, R,SR,SR,S, or S,RS,RS,R, I must have the full stereochemical structure (wedge-dash/Fischer/Newman/etc.) of the compound.

Why the answer cannot be determined from the given data

Absolute configuration depends on:

  1. The identity of substituents attached to each stereocenter.
  2. CIP priority order at each stereocenter.
  3. 3D orientation of the groups (towards/away/in-plane).

Without the structure, none of these can be assigned reliably.

Evaluation of options

Since the molecular structure is absent, the following cannot be justified:

  • A: S,SS,SS,S
  • B: R,RR,RR,R
  • C: R,SR,SR,S
  • D: S,RS,RS,R

So, from the information supplied, no option can be derived mathematically or chemically.

Comparison with stored correct answer

The stored correct answer is B (R,RR,RR,R), but because the actual compound/diagram is missing, I cannot verify that choice.

Hence I must disagree with the stored answer based on insufficient information, not because R,RR,RR,R is necessarily wrong.

What is needed

Please provide the structure/image/name of the compound so I can assign the absolute configuration step-by-step using CIP rules.

PreviousNext

More from Basics of Organic Chemistry

  • The electrophile, E⊕ attacks the benzene ring to generate the intermediate σ− complex. Of the following, which σ− complex is lowest energy?2008 · MCQ
  • The correct decreasing order of priority for the functional groups of organic compounds in the IUPAC system of nomenclature is2008 · MCQ
  • Which of the following molecules is expected to rotate the plane of plane - polarized light?2007 · MCQ
  • Includes diagram2007 · MCQ
  • Which one of the following conformation of cyclohexane is chiral?2007 · MCQ
  • Presence of a nitro group in a benzene ring2007 · MCQ
  • CH3​Br + Nu− → CH3​ - Nu + Br− The decreasing order of the rate of the above reaction with nucleophiles (Nu–) A to D is [Nu– = (A) PhO–, (B) AcO–, (C) HO–, (D) CH3​O–]2006 · MCQ
  • The IUPAC name of the compound shown below is : Includes diagram2006 · MCQ