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Basics of Organic Chemistry question

2003 · Shift 0 · Q13
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Basics of Organic Chemistry question

2003 · Shift 0 · Q13

JEE MainChemistryBasics of Organic ChemistryMCQ+4 / −1
The general formula CnH2nO2C_nH_{2n}O_2Cn​H2n​O2​ could be for open chain
  1. A
    carboxylic acids
  2. B
    diols
  3. C
    dialdehydes
  4. D
    deketones
View written solutionFree

Correct answer: A

  1. Given general formula

    We need to identify which open-chain compound class can have the molecular formula CnH2nO2.C_nH_{2n}O_2.Cn​H2n​O2​.

  2. Check each option one by one

    Option A: Carboxylic acids

    The general formula of a saturated open-chain monocarboxylic acid is RCOOH,RCOOH,RCOOH, where R=Cn−1H2(n−1)+1=Cn−1H2n−1R = C_{n-1}H_{2(n-1)+1} = C_{n-1}H_{2n-1}R=Cn−1​H2(n−1)+1​=Cn−1​H2n−1​.

    So, RCOOH=CnH2nO2.RCOOH = C_nH_{2n}O_2.RCOOH=Cn​H2n​O2​.

    Example: acetic acid CH3COOH=C2H4O2CH_3COOH = C_2H_4O_2CH3​COOH=C2​H4​O2​.

    Therefore, Option A fits.


    Option B: Diols

    A saturated open-chain diol has general formula CnH2n+2O2.C_nH_{2n+2}O_2.Cn​H2n+2​O2​.

    Example: ethylene glycol C2H6O2C_2H_6O_2C2​H6​O2​.

    This is not equal to CnH2nO2C_nH_{2n}O_2Cn​H2n​O2​.

    Therefore, Option B does not fit.


    Option C: Dialdehydes

    An open-chain dialdehyde has two terminal −CHO-CHO−CHO groups.

    Start from alkane formula: CnH2n+2C_nH_{2n+2}Cn​H2n+2​

    Converting two terminal −CH3-CH_3−CH3​ groups into two −CHO-CHO−CHO groups removes 444 H and adds 222 O: CnH2n+2→CnH2n−2O2.C_nH_{2n+2} \to C_nH_{2n-2}O_2.Cn​H2n+2​→Cn​H2n−2​O2​.

    Example: glyoxal is C2H2O2C_2H_2O_2C2​H2​O2​.

    So dialdehydes have formula CnH2n−2O2,C_nH_{2n-2}O_2,Cn​H2n−2​O2​, not CnH2nO2C_nH_{2n}O_2Cn​H2n​O2​.

    Therefore, Option C does not fit.


    Option D: Deketones

    An open-chain diketone has two ketone groups.

    Compared to alkane CnH2n+2C_nH_{2n+2}Cn​H2n+2​, introduction of two ketone groups removes 444 H and adds 222 O: CnH2n+2→CnH2n−2O2.C_nH_{2n+2} \to C_nH_{2n-2}O_2.Cn​H2n+2​→Cn​H2n−2​O2​.

    Example: butane-2,3-dione is C4H6O2C_4H_6O_2C4​H6​O2​.

    So deketones also have formula CnH2n−2O2.C_nH_{2n-2}O_2.Cn​H2n−2​O2​.

    Therefore, Option D does not fit.

  3. Conclusion

    The only open-chain class matching CnH2nO2C_nH_{2n}O_2Cn​H2n​O2​ is carboxylic acids.

  4. Comparison with stored correct answer

    Stored correct answer: A

    Derived answer: A

    Hence, the derived answer agrees with the stored correct answer.

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