JEE MainChemistryAldehydes Ketones and Carboxylic AcidsMCQ+4 / −1
Which of the following reagent is used for the following reaction ?
- AMolybdenum oxide
- BManganese acetate
- CCopper at high temperature and pressure
- DPotassium permanganate
View written solutionFree
Correct answer: A
-
Identify the transformation
The reaction is:
That is, propane is being converted to propanal.
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What type of reaction is this?
We are converting an alkane into an aldehyde by controlled oxidation:
This is not a common oxidation with strong oxidizing agents, because strong oxidants usually over-oxidize the compound.
-
Check each reagent
A. Molybdenum oxide
- Higher alkanes can be oxidized in a controlled way using catalysts like molybdenum oxide to give aldehydes.
- Thus propane can give propanal under controlled catalytic oxidation.
- So this is a suitable reagent.
B. Manganese acetate
- This is not the standard reagent for direct conversion of propane to propanal.
- Not correct here.
C. Copper at high temperature and pressure
- Copper is generally used in dehydrogenation of alcohols, e.g.
- But here the starting compound is an alkane, not an alcohol.
- So this is not correct.
D. Potassium permanganate
- is a strong oxidizing agent.
- It would not selectively stop at aldehyde in such a transformation.
- Hence not correct.
-
Conclusion
The correct reagent is:
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Comparison with stored answer
Stored correct answer: A
My derived answer is also A, so they agree.
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