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Aldehydes Ketones and Carboxylic Acids question

2021 · 24 Feb · Shift 1 · Q2
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Aldehydes Ketones and Carboxylic Acids question

2021 · 24 Feb · Shift 1 · Q2

JEE MainChemistryAldehydes Ketones and Carboxylic AcidsMCQ+4 / −1
Which of the following reagent is used for the following reaction ? CH3CH2CH3⟶?CH3CH2CHO\mathrm{CH}_3 \mathrm{CH}_2 \mathrm{CH}_3 \stackrel{?}{\longrightarrow} \mathrm{CH}_3 \mathrm{CH}_2 \mathrm{CHO}CH3​CH2​CH3​⟶?​CH3​CH2​CHO
  1. A
    Molybdenum oxide
  2. B
    Manganese acetate
  3. C
    Copper at high temperature and pressure
  4. D
    Potassium permanganate
View written solutionFree

Correct answer: A

  1. Identify the transformation

    The reaction is: CH3CH2CH3⟶CH3CH2CHO\mathrm{CH_3CH_2CH_3} \longrightarrow \mathrm{CH_3CH_2CHO}CH3​CH2​CH3​⟶CH3​CH2​CHO

    That is, propane is being converted to propanal.

  2. What type of reaction is this?

    We are converting an alkane into an aldehyde by controlled oxidation: R−CH3→R−CHO\mathrm{R-CH_3} \rightarrow \mathrm{R-CHO}R−CH3​→R−CHO

    This is not a common oxidation with strong oxidizing agents, because strong oxidants usually over-oxidize the compound.

  3. Check each reagent

    A. Molybdenum oxide

    • Higher alkanes can be oxidized in a controlled way using catalysts like molybdenum oxide to give aldehydes.
    • Thus propane can give propanal under controlled catalytic oxidation.
    • So this is a suitable reagent.

    B. Manganese acetate

    • This is not the standard reagent for direct conversion of propane to propanal.
    • Not correct here.

    C. Copper at high temperature and pressure

    • Copper is generally used in dehydrogenation of alcohols, e.g. RCH2OH→573 KCuRCHO\mathrm{RCH_2OH} \xrightarrow[573\,K]{Cu} \mathrm{RCHO}RCH2​OHCu573K​RCHO
    • But here the starting compound is an alkane, not an alcohol.
    • So this is not correct.

    D. Potassium permanganate

    • KMnO4\mathrm{KMnO_4}KMnO4​ is a strong oxidizing agent.
    • It would not selectively stop at aldehyde in such a transformation.
    • Hence not correct.
  4. Conclusion

    The correct reagent is: A. Molybdenum oxide\boxed{\text{A. Molybdenum oxide}}A. Molybdenum oxide​

  5. Comparison with stored answer

    Stored correct answer: A

    My derived answer is also A, so they agree.

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