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Aldehydes Ketones and Carboxylic Acids question

2021 · 25 Feb · Shift 2 · Q21
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Aldehydes Ketones and Carboxylic Acids question

2021 · 25 Feb · Shift 2 · Q21

JEE MainChemistryAldehydes Ketones and Carboxylic AcidsNumerical+4 / −1
The number of compound/s given below which contain/s -COOH group is ‾\underline{\hspace{2cm}}​. (Integer answer) (A) Sulphanilic acid (B) Picric acid (C) Aspirin (D) Ascorbic acid
Numerical answer
View written solutionFree

Correct answer: 1

  1. We need to count how many of the given compounds contain the carboxylic acid group (−COOH)(-COOH)(−COOH).

  2. Check each compound:

    (A) Sulphanilic acid
    Structure: H2N−C6H4−SO3HH_2N{-}C_6H_4{-}SO_3HH2​N−C6​H4​−SO3​H
    It contains sulphonic acid group (−SO3H)(-SO_3H)(−SO3​H), not carboxylic acid (−COOH)(-COOH)(−COOH).
    So, does not contain −COOH-COOH−COOH.

    (B) Picric acid
    Picric acid is 2,4,62,4,62,4,6-trinitrophenol.
    It contains a phenolic (−OH)(-OH)(−OH) group, not (−COOH)(-COOH)(−COOH).
    So, does not contain −COOH-COOH−COOH.

    (C) Aspirin
    Aspirin is acetylsalicylic acid. Its structure contains one carboxylic acid group (−COOH)(-COOH)(−COOH).
    So, contains −COOH-COOH−COOH.

    (D) Ascorbic acid
    Ascorbic acid (Vitamin C) is an enediol lactone. Despite the name "acid", it does not contain a carboxylic acid group (−COOH)(-COOH)(−COOH).
    So, does not contain −COOH-COOH−COOH.

  3. Total compounds containing −COOH-COOH−COOH:

111

Therefore, the required integer answer is:

1\boxed{1}1​

  1. Comparison with stored correct answer:
    Stored correct answer = 111
    Derived answer = 111
    Hence, they agree.
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