JEE MainChemistryAldehydes Ketones and Carboxylic AcidsMCQ+4 / −1
The increasing order of the acidity of the -hydrogen of the following compounds is : 

- A(C) < (A) < (B) < (D)
- B(B) < (C) < (A) < (D)
- C(A) < (C) < (D) < (B)
- D(D) < (C) < (A) < (B)
View written solutionFree
Correct answer: D
To compare the acidity of the -hydrogen, we use the stability of the conjugate base formed after removal of an -H.
1. Key idea
The more stable the enolate/carbanion formed, the more acidic the -hydrogen.
Stability of the conjugate base increases when:
- The negative charge is better delocalized by resonance.
- Electron-withdrawing groups are present.
- More carbonyl groups are available to stabilize the anion.
2. General acidity trend of compounds with -hydrogen
Typical order is:
- Simple ketone/aldehyde: less acidic
- Ester: somewhat acidic
- 1,3-dicarbonyl compounds: much more acidic
- Compounds where the anion is stabilized by two strong electron-withdrawing carbonyl groups are the most acidic
Thus, among the given compounds, the one with least stabilization of the conjugate base will have the least acidic -H, and the one with maximum stabilization will have the most acidic -H.
From the structures implied in the question, the increasing order comes out as:
3. Checking options
- Option A: — incorrect
- Option B: — incorrect
- Option C: — incorrect
- Option D: — correct
4. Final answer
The increasing order of acidity of the -hydrogen is
So, the correct option is D.
More from Aldehydes Ketones and Carboxylic Acids
- Which of the following derivatives of alcohols is unstable in an aqueous base?2020 · MCQ
- In the following reaction sequence the major products A and B are : Includes diagram2020 · MCQ
- The major products of the following reaction are : Includes diagram2020 · MCQ
- Consider the following reactions 'A' is : Includes diagram2020 · MCQ
- The correct match between Item-I (starting material) and Item-II (reagent) for the preparation of benzaldehyde is : Includes table2020 · MCQ
- What is the product of following reaction ? Includes diagram2020 · MCQ
- The predominant intermolecular forces present in ethyl acetate, a liquid, are:2020 · MCQ
- The most suitable reagent for the given conversion is : Includes diagram2020 · MCQ