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Aldehydes Ketones and Carboxylic Acids question

2020 · 8 Jan · Shift 1 · Q20
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Aldehydes Ketones and Carboxylic Acids question

2020 · 8 Jan · Shift 1 · Q20

JEE MainChemistryAldehydes Ketones and Carboxylic AcidsMCQ+4 / −1
The most suitable reagent for the given conversion is : JEE Main 2020 (Online) 8th January Morning Slot Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 182 English
  1. A
    LiAlH4LiAlH_4LiAlH4​
  2. B
    B2H6B_2H_6B2​H6​
  3. C
    NaBH4NaBH_4NaBH4​
  4. D
    H2H_2H2​/Pd
View written solutionFree

Correct answer: B

  1. Identify the likely transformation

    This question belongs to the chapter aldehydes, ketones and carboxylic acids and asks for the most suitable reagent among:

    • LiAlH4LiAlH_4LiAlH4​
    • B2H6B_2H_6B2​H6​
    • NaBH4NaBH_4NaBH4​
    • H2/PdH_2/PdH2​/Pd

    In this set of reagents, the key distinction is their reducing ability toward different carbonyl derivatives.

  2. Recall the reducing behavior of each reagent

    (A) LiAlH4LiAlH_4LiAlH4​

    • Very strong reducing agent.
    • Reduces aldehydes, ketones, acids, esters, acid chlorides, etc.
    • Often not called the most suitable when a more selective reagent exists.

    (B) B2H6B_2H_6B2​H6​

    • Especially suitable for reducing carboxylic acids to primary alcohols.
    • More selective than LiAlH4LiAlH_4LiAlH4​ in such conversions.

    (C) NaBH4NaBH_4NaBH4​

    • Mild reducing agent.
    • Reduces aldehydes and ketones, but generally does not reduce carboxylic acids.

    (D) H2/PdH_2/PdH2​/Pd

    • Catalytic hydrogenation can reduce some unsaturated systems and aldehydes/ketones under suitable conditions, but is not the standard most suitable reagent for converting carboxylic acids to alcohols.
  3. Infer the intended conversion

    Since the stored correct answer is B2H6B_2H_6B2​H6​, the intended conversion is most reasonably the reduction of a carboxylic acid to a primary alcohol:

    RCOOH⟶RCH2OHRCOOH \longrightarrow RCH_2OHRCOOH⟶RCH2​OH

    For this transformation, the most suitable reagent is:

    B2H6B_2H_6B2​H6​

  4. Check the options systematically

    • A: LiAlH4LiAlH_4LiAlH4​ — can do the reduction, but not the most suitable/selective.
    • B: B2H6B_2H_6B2​H6​ — best suited for reducing carboxylic acids to alcohols.
    • C: NaBH4NaBH_4NaBH4​ — not effective for carboxylic acids.
    • D: H2H_2H2​/Pd — not the standard best reagent here.
  5. Final answer

    Therefore, the most suitable reagent is:

    B2H6\boxed{B_2H_6}B2​H6​​

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