Sign in
12thPass logo
New chatPYQ LibraryDoubtsRank report
Sign in to see Recents

Your guest activity stays on this device

Sign in to save progress →
Sign in

Aldehydes Ketones and Carboxylic Acids question

2020 · 8 Jan · Shift 1 · Q19
Guest · filters and generic practice availableBrowsing as a guest · PYQ filters and generic practice are available. Sign in only for personalised features and saved progress.
  1. PYQ Library
  2. /JEE Main
  3. /Chemistry
  4. /Aldehydes Ketones and Carboxylic Acids
  5. /2020 · 8 Jan · Shift 1 · Q19

Aldehydes Ketones and Carboxylic Acids question

2020 · 8 Jan · Shift 1 · Q19

JEE MainChemistryAldehydes Ketones and Carboxylic AcidsMCQ+4 / −1
The predominant intermolecular forces present in ethyl acetate, a liquid, are:
  1. A
    Dipole-dipole and hydrogen bonding
  2. B
    hydrogen bonding and London dispersion
  3. C
    London dispersion, dipole-dipole and hydrogen bonding
  4. D
    London dispersion and dipole-dipole
View written solutionFree

Correct answer: D

  1. Identify the compound

    Ethyl acetate is an ester with structure: CH3COOCH2CH3\mathrm{CH_3COOCH_2CH_3}CH3​COOCH2​CH3​

  2. Check for possible intermolecular forces

    The main intermolecular forces to consider are:

    • London dispersion forces
    • Dipole-dipole interactions
    • Hydrogen bonding
  3. Does ethyl acetate show London dispersion forces?

    Yes. All molecules exhibit London dispersion forces due to temporary induced dipoles.

  4. Does ethyl acetate show dipole-dipole interactions?

    Yes. Ethyl acetate is a polar molecule because it contains a polar ester group: R−COOR′\mathrm{R-COOR'}R−COOR′ The carbonyl group C=O\mathrm{C=O}C=O creates a permanent dipole, so molecules attract via dipole-dipole forces.

  5. Does ethyl acetate show hydrogen bonding between its own molecules?

    No. For hydrogen bonding in a pure liquid, the molecule must contain a hydrogen directly bonded to highly electronegative atoms like O\mathrm{O}O, N\mathrm{N}N, or F\mathrm{F}F.

    In ethyl acetate, there is oxygen present, so it can accept hydrogen bonds, but it has no O−H\mathrm{O-H}O−H or N−H\mathrm{N-H}N−H bond to donate hydrogen bonds.

    Therefore, pure ethyl acetate does not exhibit intermolecular hydrogen bonding among its own molecules.

  6. Conclusion

    The predominant intermolecular forces in liquid ethyl acetate are: London dispersion forces and dipole-dipole interactions\text{London dispersion forces and dipole-dipole interactions}London dispersion forces and dipole-dipole interactions

  7. Option analysis

    • A: Dipole-dipole and hydrogen bonding →\rightarrow→ Incorrect (no self hydrogen bonding)
    • B: Hydrogen bonding and London dispersion →\rightarrow→ Incorrect
    • C: London dispersion, dipole-dipole and hydrogen bonding →\rightarrow→ Incorrect
    • D: London dispersion and dipole-dipole →\rightarrow→ Correct

Therefore, the correct answer is D.

PreviousNext

More from Aldehydes Ketones and Carboxylic Acids

  • The most suitable reagent for the given conversion is : Includes diagram2020 · MCQ
  • An unsaturated hydrocarbon X absorbs two hydrogen molecules on catalytic hydrogenation and also gives following reaction : B(3 - oxo - hexanedicarboxylic acid) X will be :- Includes diagram2020 · MCQ
  • Identify (A) in the following reaction sequence : Includes diagram2020 · MCQ
  • In the following reaction A is : Includes diagram2020 · MCQ
  • Consider the following reactions The mass percentage of carbon in A is ​. Includes diagram2020 · Numerical
  • The major product of the following reaction is : Includes diagram2019 · MCQ
  • The major product of the following reaction is : Includes diagram2019 · MCQ
  • The major product obtained in the following reaction is Includes diagram2019 · MCQ