Reason R : Fluoro is a stronger electron withdrawing group than Chloro group. In the light of the above statements, choose the correct answer from the options given below:- ABoth A and R are correct but R is NOT the correct explanation of A
- BA is false but R is true
- CA is true but R is false
- DBoth A and R are correct and R is the correct explanation of A
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Correct answer: A
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Interpret the assertion
The question refers to three compounds whose acidic order is claimed to be:
From the statement involving fluoro and chloro substituents in the chapter Alcohols, Phenols and Ethers, this is the standard comparison of substituted phenols where acidity depends on the electron-withdrawing effect of halogens and their position.
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Effect of halogen substituents on phenol acidity
- Halogens show effect (electron withdrawing inductive effect), which tends to increase acidity by stabilizing the phenoxide ion.
- Halogens also show effect (lone pair donation by resonance), especially at ortho and para positions, which tends to decrease acidity.
Among halogens: so fluoro-substituted phenol is generally more acidic than chloro-substituted phenol when comparable structures are considered.
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Check Assertion A
Since the assertion says the acidity order is: and this corresponds to the known order where the compound with stronger electron-withdrawing substituent is more acidic, the assertion is correct.
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Check Reason R
Reason states:
Fluoro is a stronger electron withdrawing group than Chloro group.
This is true because fluorine has higher electronegativity and stronger effect than chlorine.
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Does R correctly explain A?
Even though the reason is true, it is not sufficient by itself to explain the full acidity order of substituted phenols, because acidity here is influenced by:
- inductive effect (),
- resonance effect (),
- and often the position of substituent.
So merely stating that is more electron withdrawing than does not completely explain the whole order .
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Conclusion
- Assertion A: True
- Reason R: True
- But R is not the correct explanation of A.
Therefore, the correct option is:
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