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Alcohols Phenols and Ethers question

2023 · 25 Jan · Shift 1 · Q3
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Alcohols Phenols and Ethers question

2023 · 25 Jan · Shift 1 · Q3

JEE MainChemistryAlcohols Phenols and EthersMCQ+4 / −1
In the cumene to phenol preparation in presence of air, the intermediate is
  1. A
    JEE Main 2023 (Online) 25th January Morning Shift Chemistry - Alcohols, Phenols and Ethers Question 49 English Option 1
  2. B
    JEE Main 2023 (Online) 25th January Morning Shift Chemistry - Alcohols, Phenols and Ethers Question 49 English Option 2
  3. C
    JEE Main 2023 (Online) 25th January Morning Shift Chemistry - Alcohols, Phenols and Ethers Question 49 English Option 3
  4. D
    JEE Main 2023 (Online) 25th January Morning Shift Chemistry - Alcohols, Phenols and Ethers Question 49 English Option 4
View written solutionFree

Correct answer: D

  1. Identify the reaction mentioned

    The question refers to the industrial preparation of phenol from cumene in presence of air. This is the cumene process.

  2. Write the key steps of the cumene process

    Cumene is isopropylbenzene. In presence of air (oxygen), cumene first undergoes oxidation to form cumene hydroperoxide.

    Cumene→airO2Cumene hydroperoxide\text{Cumene} \xrightarrow[\text{air}]{O_2} \text{Cumene hydroperoxide}CumeneO2​air​Cumene hydroperoxide

    Then, on acidic cleavage:

    Cumene hydroperoxide→H+Phenol+Acetone\text{Cumene hydroperoxide} \xrightarrow{H^+} \text{Phenol} + \text{Acetone}Cumene hydroperoxideH+​Phenol+Acetone

  3. Identify the intermediate

    Therefore, the intermediate formed in the preparation of phenol from cumene in presence of air is:

    Cumene hydroperoxide\boxed{\text{Cumene hydroperoxide}}Cumene hydroperoxide​

  4. Compare with stored answer

    The stored correct answer is D. In standard MCQs for this question, option D corresponds to cumene hydroperoxide.

    Hence, my derived answer agrees with the stored answer.

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