Sign in
12thPass logo
New chatPYQ LibraryDoubtsRank report
Sign in to see Recents

Your guest activity stays on this device

Sign in to save progress →
Sign in

Alcohols Phenols and Ethers question

2023 · 11 Apr · Shift 1 · Q20
Guest · filters and generic practice availableBrowsing as a guest · PYQ filters and generic practice are available. Sign in only for personalised features and saved progress.
  1. PYQ Library
  2. /JEE Main
  3. /Chemistry
  4. /Alcohols Phenols and Ethers
  5. /2023 · 11 Apr · Shift 1 · Q20

Alcohols Phenols and Ethers question

2023 · 11 Apr · Shift 1 · Q20

JEE MainChemistryAlcohols Phenols and EthersNumerical+4 / −1
JEE Main 2023 (Online) 11th April Morning Shift Chemistry - Alcohols, Phenols and Ethers Question 39 English The number of hyperconjugation structures involved to stabilize carbocation formed in the above reaction is ‾\underline{\hspace{2cm}}​.
Numerical answer
View written solutionFree

Correct answer: 7

  1. Concept used

    The number of hyperconjugative structures stabilizing a carbocation equals the number of α\alphaα-hydrogen atoms present on the carbon atom(s) adjacent to the positively charged carbon.

  2. Carbocation formed

    In the given reaction, the carbocation formed is the tert-butyl carbocation:

    (CH3)3C+(CH_3)_3C^+(CH3​)3​C+

    Here, the positively charged carbon is attached to three methyl groups.

  3. Count the α\alphaα-hydrogens

    Each adjacent methyl group, CH3CH_3CH3​, contributes 3 hydrogens.

    So total α\alphaα-hydrogens are:

    3+3+3=93 + 3 + 3 = 93+3+3=9

  4. Hyperconjugative structures

    For carbocations, each α\alphaα-hydrogen gives one no-bond resonance (hyperconjugative) structure.

    Hence, the number of hyperconjugation structures is:

    999

  5. Comparison with stored answer

    Stored correct answer = 777

    My derived answer = 999

    These do not match.

    A value of 777 would correspond to the convention of counting total canonical forms including the original carbocation structure for a carbocation with 666 hyperconjugative forms, or it may be due to a different carbocation than the usual tert-butyl case. But for the standard carbocation (CH3)3C+(CH_3)_3C^+(CH3​)3​C+, the number of hyperconjugative structures is clearly 999.

PreviousNext

More from Alcohols Phenols and Ethers

  • The ratio x/y on completion of the above reaction is ​. Includes diagram2023 · Numerical
  • Product [X] formed in the above reaction is : Includes diagram2023 · MCQ
  • Compound 'B' is Includes diagram2023 · MCQ
  • Correct statements for the given reaction are : A. Compound 'B' is aromatic B. The completion of above reaction is very slow C. 'A' shows tautomerism D. The bond lengths of C−C in compound B are found to be same Choose the… Includes diagram2023 · MCQ
  • 2-Methyl propyl bromide reacts with C2​H5​O− and gives 'A' whereas on reaction with C2​H5​OH it gives 'B'. The mechanism followed in these reactions and the products…2023 · MCQ
  • Given below are two statements, one is labelled as Assertion A and the other is labelled as Reason R. Assertion A : Order of acidic nature of the following compounds is A > B > C. Reason R : Fluoro is a stronger electron withdrawing… Includes diagram2023 · MCQ
  • The major product for the following reaction is: Includes diagram2023 · MCQ
  • 'A' formed in the above reaction is Includes diagram2023 · MCQ