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Alcohols Phenols and Ethers question

2022 · 25 Jun · Shift 2 · Q12
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Alcohols Phenols and Ethers question

2022 · 25 Jun · Shift 2 · Q12

JEE MainChemistryAlcohols Phenols and EthersMCQ+4 / −1
In the given reaction JEE Main 2022 (Online) 25th June Evening Shift Chemistry - Alcohols, Phenols and Ethers Question 80 English 'A' can be
  1. A
    benzyl bromide
  2. B
    bromobenzene
  3. C
    cyclohexyl bromide
  4. D
    methyl bromide
View written solutionFree

Correct answer: B

The question image/reaction scheme is missing, so the reactant/product context needed to identify 'A' is not available.

Without the actual reaction, we cannot uniquely decide among:

  1. benzyl bromide
  2. bromobenzene
  3. cyclohexyl bromide
  4. methyl bromide

However, since the stored correct answer is given as B = bromobenzene, I check whether that is chemically plausible in typical alcohol/phenol/ether reactions.

A very common question in this chapter asks for the aryl halide used to form anisole or diphenyl ether-type products under special conditions, or to distinguish aryl halides from alkyl/benzyl halides in reactions such as Williamson synthesis / nucleophilic substitution.

Key facts:

  1. Bromobenzene is an aryl halide.
  2. Aryl halides do not undergo normal SN1S_N1SN​1 or SN2S_N2SN​2 reactions easily because:
    • the C−Br\mathrm{C-Br}C−Br bond has partial double-bond character due to resonance,
    • backside attack at an sp2sp^2sp2 carbon is difficult.
  3. In many standard organic chemistry problems, if the reaction requires behavior specific to an aryl halide, then bromobenzene is the only suitable option among the given choices.
  4. The other options are alkyl/benzyl halides and behave very differently:
    • benzyl bromide reacts very easily in substitution,
    • cyclohexyl bromide is a secondary alkyl halide,
    • methyl bromide reacts very easily via SN2S_N2SN​2.

So, although the reaction scheme is absent, option B (bromobenzene) is chemically the most likely intended answer if the problem is testing the special behavior of aryl halides in this chapter.

Derived answer

B: bromobenzene\boxed{\text{B: bromobenzene}}B: bromobenzene​

Comparison with stored answer

Stored correct answer = B

My derived answer matches the stored answer.

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