- A
- BPCC (Pyridinium Chlorochromate)
- C
- D
View written solutionFree
Correct answer: B
-
We need to convert a primary alcohol into an aldehyde .
-
This is an oxidation reaction, but the oxidizing agent must be mild enough to stop at the aldehyde stage.
-
Let us examine each reagent:
A:
This is a strong oxidizing agent. Under usual conditions, primary alcohols are often oxidized further to carboxylic acids.B: PCC (Pyridinium Chlorochromate)
PCC is a mild oxidizing agent. It oxidizes primary alcohols to aldehydes without further oxidation to carboxylic acids (especially in anhydrous medium).C:
This is a strong oxidizing agent and generally oxidizes primary alcohols all the way to carboxylic acids.D:
Acidified potassium dichromate is also a strong oxidizing agent and usually converts primary alcohols into carboxylic acids. -
Therefore, the most suitable reagent for:
is:
- Hence, the correct option is B.
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