Sign in
12thPass logo
New chatPYQ LibraryDoubtsRank report
Sign in to see Recents

Your guest activity stays on this device

Sign in to save progress →
Sign in

Alcohols Phenols and Ethers question

2014 · Shift 0 · Q14
Guest · filters and generic practice availableBrowsing as a guest · PYQ filters and generic practice are available. Sign in only for personalised features and saved progress.
  1. PYQ Library
  2. /JEE Main
  3. /Chemistry
  4. /Alcohols Phenols and Ethers
  5. /2014 · Shift 0 · Q14

Alcohols Phenols and Ethers question

2014 · Shift 0 · Q14

JEE MainChemistryAlcohols Phenols and EthersMCQ+4 / −1
The most suitable reagent for the conversion of R - CH2CH_2CH2​ - OH →\to→ R - CHO is:
  1. A
    CrO3CrO_3CrO3​
  2. B
    PCC (Pyridinium Chlorochromate)
  3. C
    KMnO4KMnO_4KMnO4​
  4. D
    K2Cr2O7K_2Cr_2O_7K2​Cr2​O7​
View written solutionFree

Correct answer: B

  1. We need to convert a primary alcohol R−CH2OHR-CH_2OHR−CH2​OH into an aldehyde R−CHOR-CHOR−CHO.

  2. This is an oxidation reaction, but the oxidizing agent must be mild enough to stop at the aldehyde stage.

  3. Let us examine each reagent:

    A: CrO3CrO_3CrO3​
    This is a strong oxidizing agent. Under usual conditions, primary alcohols are often oxidized further to carboxylic acids.

    B: PCC (Pyridinium Chlorochromate)
    PCC is a mild oxidizing agent. It oxidizes primary alcohols to aldehydes without further oxidation to carboxylic acids (especially in anhydrous medium).

    C: KMnO4KMnO_4KMnO4​
    This is a strong oxidizing agent and generally oxidizes primary alcohols all the way to carboxylic acids.

    D: K2Cr2O7K_2Cr_2O_7K2​Cr2​O7​
    Acidified potassium dichromate is also a strong oxidizing agent and usually converts primary alcohols into carboxylic acids.

  4. Therefore, the most suitable reagent for:

R−CH2OH→R−CHOR-CH_2OH \rightarrow R-CHOR−CH2​OH→R−CHO

is:

PCC\boxed{\text{PCC}}PCC​

  1. Hence, the correct option is B.
PreviousNext

More from Alcohols Phenols and Ethers

  • An unknown alcohol is treated with the “Lucas reagent” to determine whether the alcohol is primary, secondary or tertiary. Which alcohol reacts fastest and by what mechanism:2013 · MCQ
  • Arrange the following compounds in order of decreasing acidity : Includes diagram2013 · MCQ
  • Ortho–Nitrophenol is less soluble in water than p– and m– Nitrophenols because :2012 · MCQ
  • Phenol is heated with a solution of mixture of KBr and KBrO3​. The major product obtained in the above reaction is2011 · MCQ
  • From amongst the following alcohols the one that would react fastest with conc. HCl and anhydrous ZnCl2​, is2010 · MCQ
  • The major product obtained on interaction of phenol with sodium hydroxide and carbon dioxide is :2009 · MCQ
  • Phenol, when it first reacts with concentrated sulphuric acid and then with concentrated nitric acid, gives2008 · MCQ
  • In the following sequence of reactions, CH3​CH2​OH P+I2​​ A ether⟶Mg​ B HCHO​ C H2​O​ D the compound ‘D’ is2007 · MCQ