JEE MainChemistryAlcohols Phenols and EthersMCQ+4 / −1
In the following sequence of reactions, A B C D the compound ‘D’ is
- Abutanal
- Bn-butyl alcohol
- Cn-propyl alcohol
- Dpropanal
View written solutionFree
Correct answer: C
-
First reaction: ethanol with
Red phosphorus and iodine generate in situ, which converts alcohols to alkyl iodides.
So,
-
Second reaction: with Mg in dry ether
Alkyl iodide reacts with magnesium in dry ether to form the Grignard reagent.
Hence,
-
Third reaction: Grignard reagent with formaldehyde
Grignard reagents react with formaldehyde to give, after hydrolysis, a primary alcohol with one extra carbon.
First addition step:
So,
-
Fourth reaction: hydrolysis
On hydrolysis:
Therefore,
This is n-propyl alcohol.
-
Check options
- A: butanal incorrect
- B: n-butyl alcohol incorrect
- C: n-propyl alcohol correct
- D: propanal incorrect
Thus, the final compound is n-propyl alcohol.
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