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Heat and Thermodynamics question

2018 · Shift 2 · Q47
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Heat and Thermodynamics question

2018 · Shift 2 · Q47

JEE AdvancedPhysicsHeat and ThermodynamicsNumerical+3 / −1
One mole of a monatomic ideal gas undergoes an adiabatic expansion in which its volume becomes eight times its initial value. If the initial temperature of the gas is 100 K100\,K100K and the universal gas constant R=8.0J mol−1K−1,R=8.0J\,mo{l^{ - 1}}{K^{ - 1}},R=8.0Jmol−1K−1, the decrease in its internal energy, in Joule, is ‾\underline{\hspace{2cm}}​.
Numerical answer
View written solutionFree

Correct answer: 900

  1. Given data

    • Number of moles: n=1n=1n=1
    • Gas is monatomic ideal gas
    • Initial temperature: T1=100 KT_1=100\,\text{K}T1​=100K
    • Final volume: V2=8V1V_2=8V_1V2​=8V1​
    • Process: adiabatic
    • Gas constant: R=8 J mol−1K−1R=8\,\text{J mol}^{-1}\text{K}^{-1}R=8J mol−1K−1
  2. Use adiabatic relation

    For an ideal gas in an adiabatic process, TVγ−1=constantT V^{\gamma-1}=\text{constant}TVγ−1=constant

    For a monatomic gas, γ=CPCV=53\gamma=\frac{C_P}{C_V}=\frac{5}{3}γ=CV​CP​​=35​ so γ−1=23\gamma-1=\frac{2}{3}γ−1=32​

    Therefore, T1V12/3=T2V22/3T_1 V_1^{2/3}=T_2 V_2^{2/3}T1​V12/3​=T2​V22/3​

    Since V2=8V1V_2=8V_1V2​=8V1​, T2=T1(V1V2)2/3T_2=T_1\left(\frac{V_1}{V_2}\right)^{2/3}T2​=T1​(V2​V1​​)2/3 T2=100(18)2/3T_2=100\left(\frac{1}{8}\right)^{2/3}T2​=100(81​)2/3

    Now, 82/3=(23)2/3=22=48^{2/3}=(2^3)^{2/3}=2^2=482/3=(23)2/3=22=4 so (18)2/3=14\left(\frac{1}{8}\right)^{2/3}=\frac{1}{4}(81​)2/3=41​

    Hence, T2=100×14=25 KT_2=100\times \frac{1}{4}=25\,\text{K}T2​=100×41​=25K

  3. Find decrease in internal energy

    For a monatomic ideal gas, U=32nRTU=\frac{3}{2}nRTU=23​nRT

    So decrease in internal energy is ΔUdecrease=32nR(T1−T2)\Delta U_{\text{decrease}}=\frac{3}{2}nR(T_1-T_2)ΔUdecrease​=23​nR(T1​−T2​)

    Substitute values: ΔUdecrease=32×1×8×(100−25)\Delta U_{\text{decrease}}=\frac{3}{2}\times 1\times 8\times (100-25)ΔUdecrease​=23​×1×8×(100−25) =32×8×75=\frac{3}{2}\times 8\times 75=23​×8×75 =12×75=12\times 75=12×75 =900 J=900\,\text{J}=900J

  4. Final answer 900\boxed{900}900​

  5. Comparison with stored answer

    Stored correct answer = 900900900

    This matches the derived answer.

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