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Heat and Thermodynamics question

2018 · Shift 1 · Q46
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Heat and Thermodynamics question

2018 · Shift 1 · Q46

JEE AdvancedPhysicsHeat and ThermodynamicsMultiple correct+4 / −1
One mole of a monatomic ideal gas undergoes a cyclic process as shown in the figure (where VVV is the volume and TTT is the temperature). Which of the statements below is (are) true? JEE Advanced 2018 Paper 1 Offline Physics - Heat and Thermodynamics Question 57 English
  1. A
    Process I{\rm I}I is an isochoric process
  2. B
    In process II{\rm II}II, gas absorbs heat
  3. C
    In process IV{\rm IV}IV, gas releases heat
  4. D
    Process I{\rm I}I and III{\rm III}III are not isobaric
View written solutionFree

Correct answer: B, C, D

  1. Interpret the VVV–TTT graph

    For an ideal gas, PV=nRTPV = nRTPV=nRT with n=1n=1n=1 mol.

    In a VVV–TTT graph:

    • Isochoric process: V=V=V= constant ightarrow ightarrowightarrow horizontal line.
    • Isothermal process: T=T=T= constant ightarrow ightarrowightarrow vertical line.
    • Isobaric process: from PV=RTPV=RTPV=RT, at constant PPP, V=RPTV = \frac{R}{P}TV=PR​T so V∝TV \propto TV∝T, i.e. a straight line through the origin.
  2. Identify the four processes from the figure

    From the usual rectangular cyclic diagram in the VVV–TTT plane:

    • Process I: vertical segment
    • Process II: upper horizontal segment
    • Process III: vertical segment
    • Process IV: lower horizontal segment

    Therefore:

    • Process I and III are isothermal, not isobaric.
    • Process II and IV are isochoric.

    Hence:

    • Statement A: "Process I is an isochoric process" is false.
    • Statement D: "Process I and III are not isobaric" is true.
  3. Check heat in process II

    Process II is isochoric, so W=0W=0W=0 and therefore Q=ΔUQ = \Delta UQ=ΔU

    For a monatomic ideal gas, ΔU=32nRΔT\Delta U = \frac{3}{2}nR\Delta TΔU=23​nRΔT

    In process II, temperature increases along the horizontal line, so ΔT>0\Delta T>0ΔT>0. Thus, Q=32RΔT>0Q = \frac{3}{2}R\Delta T > 0Q=23​RΔT>0

    So the gas absorbs heat in process II.

    Therefore, statement B is true.

  4. Check heat in process IV

    Process IV is also isochoric, so again Q=ΔU=32RΔTQ=\Delta U = \frac{3}{2}R\Delta TQ=ΔU=23​RΔT

    In process IV, temperature decreases, so ΔT<0\Delta T<0ΔT<0. Hence, Q<0Q<0Q<0

    So the gas releases heat in process IV.

    Therefore, statement C is true.

  5. Final evaluation of options

    • A: False
    • B: True
    • C: True
    • D: True

Therefore, the correct statements are B, C, D.

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