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Heat and Thermodynamics question

2014 · Shift 1 · Q60
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Heat and Thermodynamics question

2014 · Shift 1 · Q60

JEE AdvancedPhysicsHeat and ThermodynamicsNumerical+3 / −1
A thermodynamic system is taken from an initial state i with internal energy Ui = 100 J to the final state f along two different paths iaf and ibf, as schematically shown in the figure. The work done by the system along the paths af, ib and bf are Waf = 200 J, Wib = 50 J and Wbf = 100 J respectively. The heat supplied to the system along the path iaf, ib and bf are Qiaf, Qib and Qbf respectively. If the internal energy of the system in the state b is Ub = 200 J and Qiaf = 500 J, the ratio Qbf / Qib is JEE Advanced 2014 Paper 1 Offline Physics - Heat and Thermodynamics Question 34 English
Numerical answer
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Correct answer: 2

Step-by-step Solution:

  1. Understand the First Law of Thermodynamics: The first law of thermodynamics relates the change in internal energy (ΔU\\\Delta UΔU), heat supplied to the system (QQQ), and work done by the system (WWW) as: ΔU=Q−WorQ=ΔU+W\Delta U = Q - W \quad \text{or} \quad Q = \Delta U + WΔU=Q−WorQ=ΔU+W Internal energy (UUU) is a state function, meaning its value depends only on the state of the system, not on the path taken to reach that state. Therefore, the change in internal energy between two states (e.g., from i to f) is the same regardless of the path (iaf or ibf).

  2. Calculate the Internal Energy at the Final State (UfU_fUf​) using Path iaf: We are given the following for path iaf:

    • Initial internal energy, Ui=100U_i = 100Ui​=100 J.
    • Heat supplied, Qiaf=500Q_{iaf} = 500Qiaf​=500 J. The total work done along path iaf is the sum of work done along ia and af: Wiaf=Wia+WafW_{iaf} = W_{ia} + W_{af}Wiaf​=Wia​+Waf​.
    • From the P-V diagram, the path ia is a vertical line, which represents an isochoric process (constant volume). For an isochoric process, the work done is zero. So, Wia=0W_{ia} = 0Wia​=0.
    • The work done along path af is given as Waf=200W_{af} = 200Waf​=200 J.
    • Therefore, the total work done is Wiaf=0+200=200W_{iaf} = 0 + 200 = 200Wiaf​=0+200=200 J. Now, we apply the first law of thermodynamics to the path iaf: ΔUif=Qiaf−Wiaf\Delta U_{if} = Q_{iaf} - W_{iaf}ΔUif​=Qiaf​−Wiaf​ Uf−Ui=500 J−200 JU_f - U_i = 500 \text{ J} - 200 \text{ J}Uf​−Ui​=500 J−200 J Uf−100 J=300 JU_f - 100 \text{ J} = 300 \text{ J}Uf​−100 J=300 J Uf=300 J+100 J=400 JU_f = 300 \text{ J} + 100 \text{ J} = 400 \text{ J}Uf​=300 J+100 J=400 J
  3. Calculate the Heat Supplied along Path ib (QibQ_{ib}Qib​): Now we consider the process from state i to state b.

    • Initial state: Ui=100U_i = 100Ui​=100 J.
    • Final state (for this segment): Ub=200U_b = 200Ub​=200 J (given).
    • Change in internal energy: ΔUib=Ub−Ui=200 J−100 J=100\Delta U_{ib} = U_b - U_i = 200 \text{ J} - 100 \text{ J} = 100ΔUib​=Ub​−Ui​=200 J−100 J=100 J.
    • Work done along path ib is given as Wib=50W_{ib} = 50Wib​=50 J. Using the first law for path ib: Qib=ΔUib+WibQ_{ib} = \Delta U_{ib} + W_{ib}Qib​=ΔUib​+Wib​ Qib=100 J+50 J=150 JQ_{ib} = 100 \text{ J} + 50 \text{ J} = 150 \text{ J}Qib​=100 J+50 J=150 J
  4. Calculate the Heat Supplied along Path bf (QbfQ_{bf}Qbf​): Next, we consider the process from state b to state f.

    • Initial state (for this segment): Ub=200U_b = 200Ub​=200 J.
    • Final state: Uf=400U_f = 400Uf​=400 J (calculated in Step 2).
    • Change in internal energy: ΔUbf=Uf−Ub=400 J−200 J=200\Delta U_{bf} = U_f - U_b = 400 \text{ J} - 200 \text{ J} = 200ΔUbf​=Uf​−Ub​=400 J−200 J=200 J.
    • Work done along path bf$ is given as $W_{bf} = 100$ J. (Note: Although the figure *schematically* shows $bf as an isochoric process, we must use the explicitly given numerical value for work done.) Using the first law for path bf: Qbf=ΔUbf+WbfQ_{bf} = \Delta U_{bf} + W_{bf}Qbf​=ΔUbf​+Wbf​ Qbf=200 J+100 J=300 JQ_{bf} = 200 \text{ J} + 100 \text{ J} = 300 \text{ J}Qbf​=200 J+100 J=300 J
  5. Calculate the Required Ratio: The problem asks for the ratio Qbf/QibQ_{bf} / Q_{ib}Qbf​/Qib​. QbfQib=300 J150 J=2\frac{Q_{bf}}{Q_{ib}} = \frac{300 \text{ J}}{150 \text{ J}} = 2Qib​Qbf​​=150 J300 J​=2

The final answer is 2.

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