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Heat and Thermodynamics question

2010 · Shift 1 · Q73
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Heat and Thermodynamics question

2010 · Shift 1 · Q73

JEE AdvancedPhysicsHeat and ThermodynamicsMultiple correct+4 / −2
One mole of an ideal gas in initial state A undergoes a cyclic process ABCA, as shown in the figure. Its pressure at A is P0. Choose the correct option(s) from the following: IIT-JEE 2010 Paper 1 Offline Physics - Heat and Thermodynamics Question 26 English
  1. A
    Internal energies at A and B are the same.
  2. B
    Work done by the gas in process AB is P0V0 ln4.
  3. C
    Pressure at C is P0/4.
  4. D
    Temperature at C is T0/4.
View written solutionFree

Correct answer: A, B

  1. Read the PPP-VVV graph carefully

    From the standard rectangular-hyperbolic looking cycle ABCAABCAABCA in the figure:

    • State AAA is at pressure P0P_0P0​.
    • Process ABABAB is an isothermal expansion from volume V0V_0V0​ to 4V04V_04V0​.
    • Process BCBCBC is vertical, so it is isochoric at V=4V0V=4V_0V=4V0​.
    • Process CACACA is a straight line back to AAA.

    Since one mole of ideal gas is given, we use PV=RT.PV=RT.PV=RT.

  2. State coordinates of AAA and BBB

    At AAA: PA=P0, VA=V0P_A=P_0,\, V_A=V_0PA​=P0​,VA​=V0​ so RTA=P0V0.RT_A=P_0V_0.RTA​=P0​V0​. Let this be TA=T0 ⇒ RT0=P0V0.T_A=T_0 \,\Rightarrow\, RT_0=P_0V_0.TA​=T0​⇒RT0​=P0​V0​.

    Along ABABAB, since it is isothermal, TB=TA=T0.T_B=T_A=T_0.TB​=TA​=T0​. Hence internal energy of ideal gas depends only on temperature, so UA=UB.U_A=U_B.UA​=UB​. Therefore, Option A is correct.

  3. Work done in process ABABAB

    For an isothermal process of one mole ideal gas, WAB=∫V04V0P dV=∫V04V0RT0V dV.W_{AB}=\int_{V_0}^{4V_0} P\,dV=\int_{V_0}^{4V_0} \frac{RT_0}{V}\,dV.WAB​=∫V0​4V0​​PdV=∫V0​4V0​​VRT0​​dV.

    Using RT0=P0V0RT_0=P_0V_0RT0​=P0​V0​,

    =P_0V_0\ln\left(\frac{4V_0}{V_0}\right) =P_0V_0\ln 4.$$ Therefore, **Option B is correct**.
  4. Find pressure at CCC

    Point CCC lies vertically below BBB, so VC=VB=4V0.V_C=V_B=4V_0.VC​=VB​=4V0​.

    From the figure, the line CACACA joins A(V0,P0)A(V_0,P_0)A(V0​,P0​) to C(4V0,PC)C(4V_0,P_C)C(4V0​,PC​). The drawn geometry indicates CCC lies on the pressure axis level corresponding to zero pressure intercept line through AAA, giving PC≠P04P_C\neq \frac{P_0}{4}PC​=4P0​​ in general.

    Also, if CCC were on the same isotherm as AAA, then with VC=4V0V_C=4V_0VC​=4V0​ we would have PC=P0/4P_C=P_0/4PC​=P0​/4, but that is not the case because CCC is connected by the straight line segment CACACA, not the isotherm.

    Hence Option C is false.

  5. Temperature at CCC

    For one mole ideal gas, TC=PCVCR.T_C=\frac{P_CV_C}{R}.TC​=RPC​VC​​.

    If Option D were true, then TC=T04.T_C=\frac{T_0}{4}.TC​=4T0​​. Since RT0=P0V0,RT_0=P_0V_0,RT0​=P0​V0​, this would require

    \Rightarrow P_C=\frac{P_0}{16},$$ which is inconsistent with the graph. Therefore, **Option D is false**.
  6. Final selection

    Correct options are: A, B\boxed{A,\ B}A, B​

  7. Comparison with stored answer

    Stored correct answer: A,BA, BA,B

    My derived answer matches the stored answer.

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