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Heat and Thermodynamics question

2009 · Shift 1 · Q50
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Heat and Thermodynamics question

2009 · Shift 1 · Q50

JEE AdvancedPhysicsHeat and ThermodynamicsMultiple correct+4 / −2
CVC_VCV​ and CPC_PCP​ denote the molar specific heat capacities of a gas at constant volume and constant pressure, respectively. Then
  1. A
    CP−CVC_P-C_VCP​−CV​ is larger for a diatomic ideal gas than for a monoatomic ideal gas.
  2. B
    CP+CVC_P+C_VCP​+CV​ is larger for a diatomic ideal gas than for a monoatomic ideal gas.
  3. C
    CP/CVC_P/C_VCP​/CV​ is larger for a diatomic ideal gas than for a monoatomic ideal gas.
  4. D
    CP .CVC_P~.C_VCP​ .CV​ is larger for a diatomic ideal gas than for a monoatomic ideal gas.
View written solutionFree

Correct answer: B, D

  1. Use ideal gas relations

For any ideal gas, CP−CV=RC_P - C_V = RCP​−CV​=R where RRR is the universal gas constant.

So this difference is the same for all ideal gases, independent of whether the gas is monoatomic or diatomic.

Hence, Option A is false.


  1. Write CVC_VCV​ and CPC_PCP​ for monoatomic and diatomic ideal gases

For a monoatomic ideal gas: CV=32R,CP=CV+R=52RC_V = \frac{3}{2}R, \qquad C_P = C_V + R = \frac{5}{2}RCV​=23​R,CP​=CV​+R=25​R

For a diatomic ideal gas (neglecting vibrational modes, as usual): CV=52R,CP=CV+R=72RC_V = \frac{5}{2}R, \qquad C_P = C_V + R = \frac{7}{2}RCV​=25​R,CP​=CV​+R=27​R


  1. Check Option B: CP+CVC_P + C_VCP​+CV​

For monoatomic gas: CP+CV=52R+32R=4RC_P + C_V = \frac{5}{2}R + \frac{3}{2}R = 4RCP​+CV​=25​R+23​R=4R

For diatomic gas: CP+CV=72R+52R=6RC_P + C_V = \frac{7}{2}R + \frac{5}{2}R = 6RCP​+CV​=27​R+25​R=6R

Since 6R>4R6R > 4R6R>4R Option B is true.


  1. Check Option C: CPCV\dfrac{C_P}{C_V}CV​CP​​

For monoatomic gas: γ=CPCV=52R32R=53\gamma = \frac{C_P}{C_V} = \frac{\frac{5}{2}R}{\frac{3}{2}R} = \frac{5}{3}γ=CV​CP​​=23​R25​R​=35​

For diatomic gas: γ=CPCV=72R52R=75\gamma = \frac{C_P}{C_V} = \frac{\frac{7}{2}R}{\frac{5}{2}R} = \frac{7}{5}γ=CV​CP​​=25​R27​R​=57​

Now, 53≈1.67,75=1.4\frac{5}{3} \approx 1.67, \qquad \frac{7}{5} = 1.435​≈1.67,57​=1.4

So, CPCV\frac{C_P}{C_V}CV​CP​​ is smaller for a diatomic gas than for a monoatomic gas.

Hence, Option C is false.


  1. Check Option D: CP⋅CVC_P \cdot C_VCP​⋅CV​

For monoatomic gas: CPCV=52R⋅32R=154R2C_P C_V = \frac{5}{2}R \cdot \frac{3}{2}R = \frac{15}{4}R^2CP​CV​=25​R⋅23​R=415​R2

For diatomic gas: CPCV=72R⋅52R=354R2C_P C_V = \frac{7}{2}R \cdot \frac{5}{2}R = \frac{35}{4}R^2CP​CV​=27​R⋅25​R=435​R2

Since 354R2>154R2\frac{35}{4}R^2 > \frac{15}{4}R^2435​R2>415​R2 Option D is true.


  1. Final answer

The correct options are: B,D\boxed{B, D}B,D​


  1. Comparison with stored answer

Stored correct answer: B, D

This matches our derived answer exactly.

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