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Structure of Atom question

2008 · Shift 1 · Q1
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Structure of Atom question

2008 · Shift 1 · Q1

JEE AdvancedChemistryStructure of AtomMCQ+3 / −1
STATEMENT - 1 : The plot of atomic number (y-axis) versus number of neutrons (x-axis) for stable nuclei shows a curvature towards x-axis from the line of 45o slope as the atomic number is increased. STATEMENT - 2 : Proton-proton electrostatic repulsions begin to overcome attractive forces involving protons and neutrons in heavier nuclides
  1. A
    Statement - 1 is True, Statement - 2 is True; Statement - 2 is a correct explanation for Statement - 1
  2. B
    Statement - 1 is True, Statement - 2 is True; Statement - 2 is NOT a correct explanation for Statement - 1
  3. C
    Statement - 1 is true, Statement - 2 is False
  4. D
    Statement - 1 is False, Statement - 2 is True
View written solutionFree

Correct answer: A

  1. Interpret Statement 1

For light stable nuclei, the number of neutrons NNN is approximately equal to the number of protons ZZZ. So, for small atomic number, N≈ZN \approx ZN≈Z which means a plot of atomic number ZZZ (y-axis) versus number of neutrons NNN (x-axis) lies close to the line Z=NZ = NZ=N This is a straight line of 45∘45^\circ45∘ slope.

For heavier stable nuclei, extra neutrons are needed for stability, so: N>ZN > ZN>Z Hence, on a graph of ZZZ vs NNN, the points lie below the line Z=NZ=NZ=N as NNN increases. Therefore, the stable-nuclei curve bends away from the 45∘45^\circ45∘ line towards the x-axis.

So, Statement 1 is true.


  1. Interpret Statement 2

Inside the nucleus:

  • Protons and neutrons are held together by strong nuclear forces.
  • But protons also repel each other due to electrostatic repulsion.

As atomic number ZZZ increases, the number of proton-proton pairs increases, so Coulomb repulsion becomes more significant. To maintain stability, more neutrons are required because neutrons contribute to nuclear attraction without adding electrostatic repulsion.

Thus, for heavier nuclides, proton-proton repulsions increasingly overcome or compete against the attractive interactions, requiring excess neutrons.

So, Statement 2 is true.


  1. Check whether Statement 2 explains Statement 1

Because heavier nuclei have larger proton-proton repulsion, they require more neutrons than protons for stability. That is why the stable nuclei no longer satisfy N≈ZN \approx ZN≈Z and instead have N>ZN > ZN>Z So in the plot of ZZZ vs NNN, the curve bends toward the x-axis as atomic number increases.

Therefore, Statement 2 correctly explains Statement 1.


  1. Evaluate options
  • A: Both statements are true, and Statement 2 is the correct explanation of Statement 1. ✅
  • B: Explanation part is wrong. ❌
  • C: Statement 2 is not false. ❌
  • D: Statement 1 is not false. ❌

  1. Final Answer

The correct option is: A\boxed{\text{A}}A​


  1. Comparison with stored answer

Stored correct answer: A

My derived answer: A

They agree.

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