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Structure of Atom question

2021 · Shift 2 · Q18
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Structure of Atom question

2021 · Shift 2 · Q18

JEE AdvancedChemistryStructure of AtomNumerical+4 / −1
Consider a helium (He) atom that absorbs a photon of wavelength 330 nm. The change in the velocity (in cm s −-− 1) of He atom after the photon absorption is ‾\underline{\hspace{2cm}}​. (Assume : Momentum is conserved when photon is absorbed. Use : Planck constant = 6.6 ×\times× 10 −-− 34 J s, Avogadro number = 6 ×\times× 1023 mol −-− 1, Molar mass of He = 4 g mol −-− 1)
Numerical answer
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Correct answer: 30

  1. Use conservation of momentum

When the helium atom absorbs a photon, the atom gains the photon's momentum.

Photon momentum is: p=hλp = \frac{h}{\lambda}p=λh​

So the change in velocity of the He atom is: Δv=pm=hλm\Delta v = \frac{p}{m} = \frac{h}{\lambda m}Δv=mp​=λmh​

  1. Find mass of one He atom

Given:

  • Molar mass of He =4 g mol−1= 4\,\text{g mol}^{-1}=4g mol−1
  • Avogadro number =6×1023 mol−1= 6 \times 10^{23}\,\text{mol}^{-1}=6×1023mol−1

Mass of one He atom: m=4 g6×1023=4×10−3 kg6×1023m = \frac{4\,\text{g}}{6 \times 10^{23}} = \frac{4 \times 10^{-3}\,\text{kg}}{6 \times 10^{23}}m=6×10234g​=6×10234×10−3kg​ m=46×10−26=23×10−26 kgm = \frac{4}{6} \times 10^{-26} = \frac{2}{3} \times 10^{-26}\,\text{kg}m=64​×10−26=32​×10−26kg m≈6.67×10−27 kgm \approx 6.67 \times 10^{-27}\,\text{kg}m≈6.67×10−27kg

  1. Convert wavelength into SI units

Given: λ=330 nm=330×10−9 m=3.30×10−7 m\lambda = 330\,\text{nm} = 330 \times 10^{-9}\,\text{m} = 3.30 \times 10^{-7}\,\text{m}λ=330nm=330×10−9m=3.30×10−7m

  1. Calculate photon momentum

p=hλ=6.6×10−343.3×10−7p = \frac{h}{\lambda} = \frac{6.6 \times 10^{-34}}{3.3 \times 10^{-7}}p=λh​=3.3×10−76.6×10−34​ p=2.0×10−27 kg m s−1p = 2.0 \times 10^{-27}\,\text{kg m s}^{-1}p=2.0×10−27kg m s−1

  1. Calculate change in velocity

Δv=pm=2.0×10−276.67×10−27\Delta v = \frac{p}{m} = \frac{2.0 \times 10^{-27}}{6.67 \times 10^{-27}}Δv=mp​=6.67×10−272.0×10−27​ Δv≈0.30 m s−1\Delta v \approx 0.30\,\text{m s}^{-1}Δv≈0.30m s−1

  1. Convert to cm s−1^{-1}−1

0.30 m s−1=30 cm s−10.30\,\text{m s}^{-1} = 30\,\text{cm s}^{-1}0.30m s−1=30cm s−1

Final Answer

30\boxed{30}30​

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