JEE AdvancedChemistrySome Basic Concepts of ChemistryNumerical+3 / −1
The treatment of an aqueous solution of of with excess KI results in a brown solution along with the formation of a precipitate. Passing through this brown solution gives another precipitate . The amount of (in ) is . [Given: Atomic mass of ]
Numerical answer
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Correct answer: 0.31TO0.33
- Reaction of with excess KI
Copper(II) ions oxidize iodide ions to iodine, and themselves get reduced to copper(I) iodide precipitate.
The reaction is:
So, from mol of , we get mol of .
The brown solution is due to dissolved .
- Moles of
Molar mass of :
Thus,
So, moles of mol.
- Moles of iodine formed
Using
Therefore,
- Reaction of iodine with
Hydrogen sulfide reduces iodine to iodide and itself gets oxidized to sulfur:
Thus, mol of gives mol of sulfur precipitate .
So,
- Mass of precipitate
Since ,
- Final Answer
As an integer-type entry style, the numerical value is:
Here the asked amount in grams is clearly .
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