JEE AdvancedChemistrySome Basic Concepts of ChemistryNumerical+3 / −1
In the chemical reaction between stoichiometric quantities of and in weakly basic solution, what is the number of moles of released for 4 moles of consumed?
Numerical answer
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Correct answer: 6
- Identify the redox changes in weakly basic medium
In weakly basic solution:
- Permanganate is reduced from in to where Mn is .
- Iodide is oxidized to iodine:
- Write the reduction half-reaction for permanganate in basic medium
The balanced reduction half-reaction is:
So, 1 mole of gains 3 moles of electrons.
- Write the oxidation half-reaction for iodide
So, 1 mole of formed corresponds to 2 moles of electrons released.
- Match electrons for 4 moles of
Since 1 mole of contains 1 mole of ,
For 4 moles of :
These 12 electrons must come from oxidation of iodide.
- Find moles of formed
From
2 electrons produce 1 mole of .
Therefore,
- Final answer
For 4 moles of consumed, the moles of released are:
- Comparison with stored answer
Stored correct answer = 6, which matches the derived result.
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