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Some Basic Concepts of Chemistry question

2020 · Shift 2 · Q3
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Some Basic Concepts of Chemistry question

2020 · Shift 2 · Q3

JEE AdvancedChemistrySome Basic Concepts of ChemistryNumerical+3 / −1
In the chemical reaction between stoichiometric quantities of KMnO4KMnO_4KMnO4​ and KIKIKI in weakly basic solution, what is the number of moles of I2I_2I2​ released for 4 moles of KMnO4KMnO_4KMnO4​ consumed?
Numerical answer
View written solutionFree

Correct answer: 6

  1. Identify the redox changes in weakly basic medium

In weakly basic solution:

  • Permanganate is reduced from Mn+7Mn^{+7}Mn+7 in MnO4−MnO_4^-MnO4−​ to MnO2MnO_2MnO2​ where Mn is +4+4+4.
  • Iodide is oxidized to iodine: 2I−→I2+2e−2I^- \rightarrow I_2 + 2e^-2I−→I2​+2e−
  1. Write the reduction half-reaction for permanganate in basic medium

The balanced reduction half-reaction is: MnO4−+2H2O+3e−→MnO2+4OH−MnO_4^- + 2H_2O + 3e^- \rightarrow MnO_2 + 4OH^-MnO4−​+2H2​O+3e−→MnO2​+4OH−

So, 1 mole of MnO4−MnO_4^-MnO4−​ gains 3 moles of electrons.

  1. Write the oxidation half-reaction for iodide

2I−→I2+2e−2I^- \rightarrow I_2 + 2e^-2I−→I2​+2e−

So, 1 mole of I2I_2I2​ formed corresponds to 2 moles of electrons released.

  1. Match electrons for 4 moles of KMnO4KMnO_4KMnO4​

Since 1 mole of KMnO4KMnO_4KMnO4​ contains 1 mole of MnO4−MnO_4^-MnO4−​,

For 4 moles of KMnO4KMnO_4KMnO4​: 4×3=12 moles of electrons are accepted4 \times 3 = 12 \text{ moles of electrons are accepted}4×3=12 moles of electrons are accepted

These 12 electrons must come from oxidation of iodide.

  1. Find moles of I2I_2I2​ formed

From 2I−→I2+2e−2I^- \rightarrow I_2 + 2e^-2I−→I2​+2e−

2 electrons produce 1 mole of I2I_2I2​.

Therefore, moles of I2=122=6\text{moles of } I_2 = \frac{12}{2} = 6moles of I2​=212​=6

  1. Final answer

For 4 moles of KMnO4KMnO_4KMnO4​ consumed, the moles of I2I_2I2​ released are: 6\boxed{6}6​

  1. Comparison with stored answer

Stored correct answer = 6, which matches the derived result.

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