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Some Basic Concepts of Chemistry question

2019 · Shift 2 · Q13
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Some Basic Concepts of Chemistry question

2019 · Shift 2 · Q13

JEE AdvancedChemistrySome Basic Concepts of ChemistryNumerical+3 / −1
The amount of water produced (in g) in the oxidation of 1 mole of rhombic sulphur by conc. HNO3HNO_3HNO3​ to a compound with the highest oxidation state of sulphur is .............. (Given data : Molar mass of water = 18 g mol −-− 1)
Numerical answer
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Correct answer: 288

Step-by-Step Solution:

  1. Identify the reactants and products.

    • The reactant is rhombic sulphur, which has the molecular formula S8S_8S8​. In its elemental form, the oxidation state of sulphur is 0.
    • The oxidizing agent is concentrated nitric acid, HNO3HNO_3HNO3​. The oxidation state of Nitrogen in HNO3HNO_3HNO3​ is +5.
    • The problem states that sulphur is oxidized to a compound with its highest oxidation state. The highest oxidation state of sulphur (a group 16 element) is +6. The common stable compound formed is sulphuric acid, H2SO4H_2SO_4H2​SO4​.
    • When concentrated HNO3HNO_3HNO3​ acts as an oxidizing agent, it is typically reduced to nitrogen dioxide, NO2NO_2NO2​, where the oxidation state of Nitrogen is +4.
    • Water (H2OH_2OH2​O) is also formed in the reaction.
  2. Write the unbalanced chemical equation. The unbalanced equation based on the identified species is: S8+HNO3→H2SO4+NO2+H2OS_8 + HNO_3 \rightarrow H_2SO_4 + NO_2 + H_2OS8​+HNO3​→H2​SO4​+NO2​+H2​O

  3. Balance the equation using the oxidation number method.

    • Oxidation half-reaction: Sulphur is oxidized from 0 to +6.

      • Change in oxidation state per S atom = +6−0=+6+6 - 0 = +6+6−0=+6.
      • Since one molecule of rhombic sulphur contains 8 atoms (S8S_8S8​), the total increase in oxidation number for one mole of S8S_8S8​ is 8×(+6)=+488 \times (+6) = +488×(+6)=+48.
    • Reduction half-reaction: Nitrogen is reduced from +5 in HNO3HNO_3HNO3​ to +4 in NO2NO_2NO2​.

      • Change in oxidation state per N atom = +4−(+5)=−1+4 - (+5) = -1+4−(+5)=−1.
    • Balance the change in oxidation states: To make the total increase in oxidation number equal to the total decrease, we need to multiply the reduction half-reaction by 48. This gives the stoichiometric ratio between S8S_8S8​ and HNO3HNO_3HNO3​ as 1:48.

    • This also implies that 1 mole of S8S_8S8​ produces 8 moles of H2SO4H_2SO_4H2​SO4​ and 48 moles of NO2NO_2NO2​.

  4. Write the partially balanced equation. 1S8+48HNO3→8H2SO4+48NO2+xH2O1 S_8 + 48 HNO_3 \rightarrow 8 H_2SO_4 + 48 NO_2 + x H_2O1S8​+48HNO3​→8H2​SO4​+48NO2​+xH2​O We need to find the coefficient 'x' for water by balancing the remaining atoms (Hydrogen and Oxygen).

  5. Balance the Hydrogen and Oxygen atoms.

    • Balance Hydrogen (H) atoms:

      • On the left-hand side (LHS): 48×1=4848 \times 1 = 4848×1=48 H atoms.
      • On the right-hand side (RHS): (8×2)+(x×2)=16+2x(8 \times 2) + (x \times 2) = 16 + 2x(8×2)+(x×2)=16+2x H atoms.
      • Equating H atoms on both sides: 48=16+2x48 = 16 + 2x48=16+2x
      • 2x=48−16=322x = 48 - 16 = 322x=48−16=32
      • x=16x = 16x=16
    • The balanced chemical equation is: S8+48HNO3→8H2SO4+48NO2+16H2OS_8 + 48 HNO_3 \rightarrow 8 H_2SO_4 + 48 NO_2 + 16 H_2OS8​+48HNO3​→8H2​SO4​+48NO2​+16H2​O

    • (Check) Balance Oxygen (O) atoms:

      • LHS: 48×3=14448 \times 3 = 14448×3=144 O atoms.
      • RHS: (8×4)+(48×2)+(16×1)=32+96+16=144(8 \times 4) + (48 \times 2) + (16 \times 1) = 32 + 96 + 16 = 144(8×4)+(48×2)+(16×1)=32+96+16=144 O atoms.
      • The equation is correctly balanced.
  6. Calculate the amount of water produced.

    • The question asks for the amount of water produced from the oxidation of 1 mole of rhombic sulphur (S8S_8S8​).
    • From the balanced equation, the stoichiometric relationship is: 1 mole of S8S_8S8​ produces 16 moles of H2OH_2OH2​O.
    • Moles of water produced = 16 mol.
  7. Convert moles of water to mass in grams.

    • Given: Molar mass of water = 18 g mol−1^{-1}−1.
    • Mass of water = Moles of water ×\times× Molar mass of water
    • Mass of water = 16 mol×18 g mol−1=288 g16 \text{ mol} \times 18 \text{ g mol}^{-1} = 288 \text{ g}16 mol×18 g mol−1=288 g.

The amount of water produced is 288 g.

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