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Correct answer: 288
Step-by-Step Solution:
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Identify the reactants and products.
- The reactant is rhombic sulphur, which has the molecular formula . In its elemental form, the oxidation state of sulphur is 0.
- The oxidizing agent is concentrated nitric acid, . The oxidation state of Nitrogen in is +5.
- The problem states that sulphur is oxidized to a compound with its highest oxidation state. The highest oxidation state of sulphur (a group 16 element) is +6. The common stable compound formed is sulphuric acid, .
- When concentrated acts as an oxidizing agent, it is typically reduced to nitrogen dioxide, , where the oxidation state of Nitrogen is +4.
- Water () is also formed in the reaction.
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Write the unbalanced chemical equation. The unbalanced equation based on the identified species is:
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Balance the equation using the oxidation number method.
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Oxidation half-reaction: Sulphur is oxidized from 0 to +6.
- Change in oxidation state per S atom = .
- Since one molecule of rhombic sulphur contains 8 atoms (), the total increase in oxidation number for one mole of is .
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Reduction half-reaction: Nitrogen is reduced from +5 in to +4 in .
- Change in oxidation state per N atom = .
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Balance the change in oxidation states: To make the total increase in oxidation number equal to the total decrease, we need to multiply the reduction half-reaction by 48. This gives the stoichiometric ratio between and as 1:48.
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This also implies that 1 mole of produces 8 moles of and 48 moles of .
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Write the partially balanced equation. We need to find the coefficient 'x' for water by balancing the remaining atoms (Hydrogen and Oxygen).
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Balance the Hydrogen and Oxygen atoms.
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Balance Hydrogen (H) atoms:
- On the left-hand side (LHS): H atoms.
- On the right-hand side (RHS): H atoms.
- Equating H atoms on both sides:
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The balanced chemical equation is:
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(Check) Balance Oxygen (O) atoms:
- LHS: O atoms.
- RHS: O atoms.
- The equation is correctly balanced.
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Calculate the amount of water produced.
- The question asks for the amount of water produced from the oxidation of 1 mole of rhombic sulphur ().
- From the balanced equation, the stoichiometric relationship is: 1 mole of produces 16 moles of .
- Moles of water produced = 16 mol.
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Convert moles of water to mass in grams.
- Given: Molar mass of water = 18 g mol.
- Mass of water = Moles of water Molar mass of water
- Mass of water = .
The amount of water produced is 288 g.
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