JEE AdvancedChemistrySolutionsNumerical+4 / −1
If the freezing point of a 0.01 molal aqueous solution of a cobalt (III) chloride-ammonia complex(which behaves as a strong electrolyte) is – 0.0558oC, the number of chloride(s) in the coordination sphere of the complex is [Kf of water = 1.86 K kg mol–1 ]
Numerical answer
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Correct answer: 1
- Use depression in freezing point formula
For a strong electrolyte: where:
So,
Thus, the van't Hoff factor is:
- Interpret
Since the complex behaves as a strong electrolyte, it dissociates completely into ions.
Let the complex be of the type:
Here:
- chloride ions are inside the coordination sphere.
- chloride ions are outside the coordination sphere and dissociate as counter ions.
On dissociation:
So total number of ions formed is:
Since for complete dissociation, number of ions equals van't Hoff factor:
Therefore,
- Conclusion
The number of chloride ions in the coordination sphere is:
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