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Electrochemistry question

2008 · Shift 2 · Q8
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Electrochemistry question

2008 · Shift 2 · Q8

JEE AdvancedChemistryElectrochemistryMCQ+3 / −1
Electrolysis of dilute aqueous NaCl solution was carried out by passing 10 milli ampere current. The time required to liberate 0.01 mol of H 2{}_22​ gas at the cathode is (1 Faraday = 96500 C mol −1{}^{-1}−1].
  1. A
    9.65 ×\times× 10 4{}^44 sec
  2. B
    19.3 ×\times× 10 4{}^44 sec
  3. C
    28.95 ×\times× 10 4{}^44 sec
  4. D
    38.6 ×\times× 10 4{}^44 sec
View written solutionFree

Correct answer: B

  1. Cathode reaction in dilute aqueous NaCl

In dilute aqueous NaCl, at the cathode water is reduced:

2H2O+2e−→H2+2OH−2H_2O + 2e^- \rightarrow H_2 + 2OH^-2H2​O+2e−→H2​+2OH−

So, to produce 1 mol of H2H_2H2​, we need 2 mol of electrons.


  1. Moles of electrons needed for 0.010.010.01 mol H2H_2H2​

Given:

n(H2)=0.01 moln(H_2)=0.01\text{ mol}n(H2​)=0.01 mol

From stoichiometry,

n(e−)=2×0.01=0.02 moln(e^-)=2\times 0.01 = 0.02\text{ mol}n(e−)=2×0.01=0.02 mol


  1. Charge required

Using:

1 Faraday=96500 C mol−11\text{ Faraday} = 96500\text{ C mol}^{-1}1 Faraday=96500 C mol−1

Required charge:

Q=n(e−)×F=0.02×96500Q = n(e^-)\times F = 0.02\times 96500Q=n(e−)×F=0.02×96500

Q=1930 CQ=1930\text{ C}Q=1930 C


  1. Use Q=ItQ = ItQ=It to find time

Current passed:

I=10 milliampere=10×10−3=0.01 AI=10\text{ milliampere}=10\times 10^{-3}=0.01\text{ A}I=10 milliampere=10×10−3=0.01 A

Hence,

t=QI=19300.01t=\frac{Q}{I} = \frac{1930}{0.01}t=IQ​=0.011930​

t=193000 st=193000\text{ s}t=193000 s

t=1.93×105 s=19.3×104 st = 1.93\times 10^5\text{ s} = 19.3\times 10^4\text{ s}t=1.93×105 s=19.3×104 s


  1. Match with options

19.3×104 s19.3\times 10^4\text{ s}19.3×104 s corresponds to Option B.


  1. Verification with stored answer

Stored correct answer: B

Derived answer: B

They match.

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