- AAqua-regia is prepared by mixing conc. and conc. in 3 : 1 (v / v) ratio
- BThe yellow colour of aqua-regia is due to the presence of and
- CReaction of gold with aqua-regia produces an anion having Au in +3 oxidation state
- DReaction of gold with aqua regia produces in the absence of air
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Correct answer: A, B, C
- What is aqua-regia?
Aqua-regia is a freshly prepared mixture of concentrated hydrochloric acid and concentrated nitric acid in the ratio: So, Option A is correct.
- Why is aqua-regia yellow?
When conc. and conc. are mixed, they react to produce species such as nitrosyl chloride and chlorine: Both and contribute to the characteristic yellow/orange appearance of aqua-regia. Hence, Option B is correct.
- Reaction of gold with aqua-regia
Gold dissolves in aqua-regia because:
- oxidizes to
- from stabilizes it as a chloro-complex
The overall reaction is commonly written as: The anion formed is: Now, for oxidation state of Au in : Let oxidation state of Au be . So, Option C is correct.
- Does gold with aqua-regia produce in absence of air?
From the standard reaction of gold with aqua-regia: The nitrogen oxide initially formed is , not . may further oxidize in air to : Therefore, in the absence of air, is not produced. So, Option D is incorrect.
- Final selection
Correct options are:
- Comparison with stored correct answer
Stored correct answer:
My derived answer matches the stored answer.
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