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D and F Block Elements question

2018 · Shift 2 · Q3
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D and F Block Elements question

2018 · Shift 2 · Q3

JEE AdvancedChemistryD and F Block ElementsMultiple correct+4 / −1
The correct option(s) to distinguish nitrate salts of Mn2+M{n^{2 + }}Mn2+ and Cu2+C{u^{2 + }}Cu2+ taken separately is (are)
  1. A
    Mn2+M{n^{2 + }}Mn2+ shows the characteristic green color in the flame test
  2. B
    Only Cu2+C{u^{2 + }}Cu2+ shows the formation of precipitate by passing H2S{H_2}SH2​S in acidic medium
  3. C
    Only Mn2+M{n^{2 + }}Mn2+ shows the formation of precipitate by passing H2S{H_2}SH2​S in faintly basic medium
  4. D
    Cu2+/CuC{u^{2 + }}/CuCu2+/Cu has higher reduction potential than Mn2+/MnM{n^{2 + }}/MnMn2+/Mn (measured under similar conditions)
View written solutionFree

Correct answer: B, D

  1. We need to distinguish nitrate salts of Mn2+Mn^{2+}Mn2+ and Cu2+Cu^{2+}Cu2+ using the given statements.
    So we test each option independently.

  1. Option A: Mn2+Mn^{2+}Mn2+ shows the characteristic green color in the flame test
  • Flame test colors are due to excitation of electrons.
  • Cu2+Cu^{2+}Cu2+ salts characteristically give a blue-green flame.
  • Mn2+Mn^{2+}Mn2+ does not give a characteristic green flame in ordinary flame test.

Therefore, Option A is false.


  1. Option B: Only Cu2+Cu^{2+}Cu2+ shows the formation of precipitate by passing H2SH_2SH2​S in acidic medium
  • In qualitative analysis, H2SH_2SH2​S in acidic medium precipitates only those metal sulfides whose solubility product is very low.
  • Cu2+Cu^{2+}Cu2+ forms black precipitate of copper sulfide: Cu2++H2S→CuS↓+2H+Cu^{2+} + H_2S \rightarrow CuS\downarrow + 2H^+Cu2++H2​S→CuS↓+2H+
  • Mn2+Mn^{2+}Mn2+ does not precipitate in acidic medium because MnSMnSMnS is not sufficiently insoluble under these conditions.

Therefore, only Cu2+Cu^{2+}Cu2+ gives precipitate in acidic medium.
So, Option B is true.


  1. Option C: Only Mn2+Mn^{2+}Mn2+ shows the formation of precipitate by passing H2SH_2SH2​S in faintly basic medium
  • In faintly basic medium, sulfide ion concentration increases.
  • Mn2+Mn^{2+}Mn2+ forms flesh-colored precipitate of MnSMnSMnS: Mn2++S2−→MnS↓Mn^{2+} + S^{2-} \rightarrow MnS\downarrowMn2++S2−→MnS↓
  • But Cu2+Cu^{2+}Cu2+ also forms CuSCuSCuS precipitate, and in fact it precipitates even in acidic medium itself.

Hence it is wrong to say only Mn2+Mn^{2+}Mn2+ shows precipitate in faintly basic medium.

Therefore, Option C is false.


  1. Option D: Cu2+/CuCu^{2+}/CuCu2+/Cu has higher reduction potential than Mn2+/MnMn^{2+}/MnMn2+/Mn

Standard reduction potentials are: E∘(Cu2+/Cu)=+0.34 VE^\circ(Cu^{2+}/Cu)=+0.34\,VE∘(Cu2+/Cu)=+0.34V E∘(Mn2+/Mn)=−1.18 VE^\circ(Mn^{2+}/Mn)=-1.18\,VE∘(Mn2+/Mn)=−1.18V

Clearly, +0.34 V>−1.18 V+0.34\,V > -1.18\,V+0.34V>−1.18V

Therefore, Cu2+/CuCu^{2+}/CuCu2+/Cu has higher reduction potential.

So, Option D is true.


  1. Final selection
  • A: False
  • B: True
  • C: False
  • D: True

Hence, the correct options are: B,D\boxed{B, D}B,D​


  1. Comparison with stored correct answer

Stored correct answer: B, D
Derived answer: B, D

They match exactly.

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