JEE AdvancedChemistryD and F Block ElementsMultiple correct+4 / −1
The correct option(s) to distinguish nitrate salts of and taken separately is (are)
- Ashows the characteristic green color in the flame test
- BOnly shows the formation of precipitate by passing in acidic medium
- COnly shows the formation of precipitate by passing in faintly basic medium
- Dhas higher reduction potential than (measured under similar conditions)
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Correct answer: B, D
- We need to distinguish nitrate salts of and using the given statements.
So we test each option independently.
- Option A: shows the characteristic green color in the flame test
- Flame test colors are due to excitation of electrons.
- salts characteristically give a blue-green flame.
- does not give a characteristic green flame in ordinary flame test.
Therefore, Option A is false.
- Option B: Only shows the formation of precipitate by passing in acidic medium
- In qualitative analysis, in acidic medium precipitates only those metal sulfides whose solubility product is very low.
- forms black precipitate of copper sulfide:
- does not precipitate in acidic medium because is not sufficiently insoluble under these conditions.
Therefore, only gives precipitate in acidic medium.
So, Option B is true.
- Option C: Only shows the formation of precipitate by passing in faintly basic medium
- In faintly basic medium, sulfide ion concentration increases.
- forms flesh-colored precipitate of :
- But also forms precipitate, and in fact it precipitates even in acidic medium itself.
Hence it is wrong to say only shows precipitate in faintly basic medium.
Therefore, Option C is false.
- Option D: has higher reduction potential than
Standard reduction potentials are:
Clearly,
Therefore, has higher reduction potential.
So, Option D is true.
- Final selection
- A: False
- B: True
- C: False
- D: True
Hence, the correct options are:
- Comparison with stored correct answer
Stored correct answer: B, D
Derived answer: B, D
They match exactly.
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