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Coordination Compounds question

2023 · Shift 1 · Q15
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  5. /2023 · Shift 1 · Q15

Coordination Compounds question

2023 · Shift 1 · Q15

JEE AdvancedChemistryCoordination CompoundsMCQ+3 / −1
Match the electronic configurations in List-I with appropriate metal complex ions in List-II and choose the correct option.

[Atomic Number: Fe=26,Mn=25,Co=27\mathrm{Fe}=26, \mathrm{Mn}=25, \mathrm{Co}=27Fe=26,Mn=25,Co=27]

List - I List - II
(P) t2g6eg0t_{2 g}^6 e_g^0t2g6​eg0​ (1) [Fe(H2O)6]2+\left[\mathrm{Fe}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+}[Fe(H2​O)6​]2+
(Q) t2g3eg2t_{2 g}^3 e_g^2t2g3​eg2​ (2) [Mn(H2O)6]2+\left[\mathrm{Mn}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+}[Mn(H2​O)6​]2+
(R) e2t23\mathrm{e}^2 \mathrm{t}_2^3e2t23​ (3) [Co(NH3)6]3+\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]^{3+}[Co(NH3​)6​]3+
(S) t2g4eg2t_{2 g}^4 e_g^2t2g4​eg2​ (4) [FeCl4]−\left[\mathrm{FeCl}_4\right]^{-}[FeCl4​]−
(5) [CoCl4]2−\left[\mathrm{CoCl}_4\right]^{2-}[CoCl4​]2−
  1. A
    P→1;Q→4;R→2;S→3\mathrm{P} \rightarrow 1 ; \mathrm{Q} \rightarrow 4 ; \mathrm{R} \rightarrow 2 ; \mathrm{S} \rightarrow 3P→1;Q→4;R→2;S→3
  2. B
    P→1;Q→2;R→4;S→5P \rightarrow 1 ; \mathrm{Q} \rightarrow 2 ; \mathrm{R} \rightarrow 4 ; \mathrm{S} \rightarrow 5P→1;Q→2;R→4;S→5
  3. C
    P→3;Q→2;R→5;S→1\mathrm{P} \rightarrow 3 ; \mathrm{Q} \rightarrow 2 ; \mathrm{R} \rightarrow 5 ; \mathrm{S} \rightarrow 1P→3;Q→2;R→5;S→1
  4. D
    P→3;Q→2;R→4;S→1\mathrm{P} \rightarrow 3 ; \mathrm{Q} \rightarrow 2 ; \mathrm{R} \rightarrow 4 ; \mathrm{S} \rightarrow 1P→3;Q→2;R→4;S→1
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