- AStatement 1 is True, Statement 2 is True; Statement 2 is a CORRECT explanation for Statement 1.
- BStatement 1 is True, Statement 2 is True; Statement 2 is a NOT CORRECT explanation for Statement 1.
- CStatement 1 is True, Statement 2 is False.
- DStatement 1 is False, Statement 2 is True.
View written solutionFree
Correct answer: B
- Identify the complex and its geometrical isomers
The complex is of the type which is an octahedral complex of the form .
Such complexes show two geometrical isomers:
- cis-
- trans-
- Check Statement 1: Are the geometrical isomers optically inactive?
For octahedral complexes of the type :
- the trans isomer is definitely optically inactive due to symmetry.
- the cis isomer is also optically inactive because it contains a plane of symmetry.
Hence, neither cis nor trans form is chiral.
So, Statement 1 is True.
- Check Statement 2: Do both geometrical isomers possess an axis of symmetry?
We examine both isomers:
(i) trans-
This has a clear symmetry axis passing through the two opposite ligands and the metal center. So it possesses an axis of symmetry.
(ii) cis-
This also has a symmetry axis (a axis) in the octahedral arrangement.
Therefore, both geometrical isomers do possess an axis of symmetry.
So, Statement 2 is True.
- Is Statement 2 the correct explanation of Statement 1?
Optical activity requires chirality, i.e. absence of improper symmetry elements such as:
- plane of symmetry,
- center of symmetry,
- etc.
Merely having an axis of symmetry does not by itself guarantee optical inactivity. Many chiral molecules can possess a proper rotation axis.
For this complex:
- the trans isomer is optically inactive mainly due to higher symmetry (including center/plane elements),
- the cis isomer is optically inactive because of a plane of symmetry, not simply because it has an axis of symmetry.
Thus, although Statement 2 is True, it is not the correct explanation of Statement 1.
- Final option
- Statement 1: True
- Statement 2: True
- Statement 2 is not the correct explanation of Statement 1
Therefore, the correct option is
- Comparison with stored correct answer
Stored correct answer: B
My derived answer: B
So, they agree.
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