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Coordination Compounds question

2008 · Shift 2 · Q13
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Coordination Compounds question

2008 · Shift 2 · Q13

JEE AdvancedChemistryCoordination CompoundsMCQ+3 / −1
Statement 1 : The geometrical isomers of the complex [M(NH 3{}_33​) 4{}_44​ Cl 2{}_22​] are optically inactive. Statement 2 : Both geometrical isomers of the complex [M(NH 3{}_33​) 4{}_44​ Cl 2{}_22​] possess axis of symmetry.
  1. A
    Statement 1 is True, Statement 2 is True; Statement 2 is a CORRECT explanation for Statement 1.
  2. B
    Statement 1 is True, Statement 2 is True; Statement 2 is a NOT CORRECT explanation for Statement 1.
  3. C
    Statement 1 is True, Statement 2 is False.
  4. D
    Statement 1 is False, Statement 2 is True.
View written solutionFree

Correct answer: B

  1. Identify the complex and its geometrical isomers

The complex is of the type [M(NH3)4Cl2][M(NH_3)_4Cl_2][M(NH3​)4​Cl2​] which is an octahedral complex of the form [MA4B2][MA_4B_2][MA4​B2​].

Such complexes show two geometrical isomers:

  • cis-[M(NH3)4Cl2][M(NH_3)_4Cl_2][M(NH3​)4​Cl2​]
  • trans-[M(NH3)4Cl2][M(NH_3)_4Cl_2][M(NH3​)4​Cl2​]

  1. Check Statement 1: Are the geometrical isomers optically inactive?

For octahedral complexes of the type [MA4B2][MA_4B_2][MA4​B2​]:

  • the trans isomer is definitely optically inactive due to symmetry.
  • the cis isomer is also optically inactive because it contains a plane of symmetry.

Hence, neither cis nor trans form is chiral.

So, Statement 1 is True.


  1. Check Statement 2: Do both geometrical isomers possess an axis of symmetry?

We examine both isomers:

(i) trans-[M(NH3)4Cl2][M(NH_3)_4Cl_2][M(NH3​)4​Cl2​]

This has a clear symmetry axis passing through the two opposite ClClCl ligands and the metal center. So it possesses an axis of symmetry.

(ii) cis-[M(NH3)4Cl2][M(NH_3)_4Cl_2][M(NH3​)4​Cl2​]

This also has a symmetry axis (a C2C_2C2​ axis) in the octahedral arrangement.

Therefore, both geometrical isomers do possess an axis of symmetry.

So, Statement 2 is True.


  1. Is Statement 2 the correct explanation of Statement 1?

Optical activity requires chirality, i.e. absence of improper symmetry elements such as:

  • plane of symmetry,
  • center of symmetry,
  • etc.

Merely having an axis of symmetry does not by itself guarantee optical inactivity. Many chiral molecules can possess a proper rotation axis.

For this complex:

  • the trans isomer is optically inactive mainly due to higher symmetry (including center/plane elements),
  • the cis isomer is optically inactive because of a plane of symmetry, not simply because it has an axis of symmetry.

Thus, although Statement 2 is True, it is not the correct explanation of Statement 1.


  1. Final option
  • Statement 1: True
  • Statement 2: True
  • Statement 2 is not the correct explanation of Statement 1

Therefore, the correct option is B\boxed{B}B​


  1. Comparison with stored correct answer

Stored correct answer: B

My derived answer: B

So, they agree.

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